Methods for forming aerosol-generating substrates having a reduced amount of tobacco specific nitrosamines
An aerosol generation and nitrosamine technology, applied in tobacco, tobacco preparation, tobacco processing, etc., can solve expensive and time-consuming problems
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[0025] N-nitrosonornicotine (NNN) and 4-(methylnitrosamine)-1-(3-pyridyl)-1-butanone (NNK) at specified concentrations (380 and 613 nA, respectively g / ml) to three different liquid aerosol-generating matrices consisting of nicotine, glycerol, propylene glycol and water (2:10:68:20, 2 :39:39:20 and 2:68:10:20 by weight). Aliquots of these solutions were placed in clear glass vials and irradiated with UV radiation (wavelength of 365 nm; nominal lamp power of 8 watts; lamp distance of 3 cm) for specified times (0, 15, 30, 60, 120 or 240 minutes). After irradiation, the samples were diluted ten-fold with water and analyzed for their nicotine, NNN and NNK content.
[0026] UV irradiation caused a time-dependent reduction of NNK and NNN in all three nicotine / glycerol / propylene glycol / water mixtures. Nicotine concentrations were not affected. Nitrosamine decay is approximately exponential with respect to irradiation time. The half-lives of NNN and NNK are in the range of 30-50 m...
example 2
[0028] A sample sheet of cast tobacco slurry having a thickness of 0.20 to 0.22 mm after drying to 195 to 200 g / m² was irradiated with UV light at a wavelength of 365 nm and an intensity of 4.5 mW / cm² for 150 minutes on each side . After further drying and cutting, irradiated cast leaf samples and non-irradiated controls were analyzed for NNK, NNN and nicotine content using mass spectrometry. The irradiated samples indicated no effect on nicotine levels, a 12% reduction in NNK content, and a 26% reduction in NNN content as compared to the control.
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