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A method for preparing manganese carbonate and ammonium sulfate potassium sulfate compound fertilizer by using electrolysis MNO2 and MN-containing waste residue in electrolysis MN production

A technology of potassium sulfate compound fertilizer and manganese carbonate, which is applied in the direction of chemical instruments and methods, potash fertilizers, manganese compounds, etc., and can solve problems such as environmental pollution

Inactive Publication Date: 2018-05-22
湘潭市环境保护科学研究院 +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] The water dissolution method is used to treat the Mn-containing waste residue in the production of electrolytic Mn. After the preparation of manganese sulfate and ammonium sulfate, there is still a large amount of Mn-containing residue discharged, which will pollute the environment.

Method used

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Examples

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Effect test

Embodiment

[0029] Measure H 2 Put 450ml into a 2000ml three-neck flask, start stirring, add 500g of Mn-containing waste residue (dry basis) with a Mn content of 4.5%, beat it into a uniform slurry, add 70ml of industrial sulfuric acid with a mass fraction of 98%, and heat up to 140°C. Stir the reaction, connect the air outlet pipe to the serpentine condensing pipe for full reflux, and start the central control after 30 minutes of reaction, take the slurry and mix it to analyze the Mn content in the slag, when the reaction is 80 minutes, the Mn content in the slag is 0.073%, stop heating, add H 2 O 200ml stirred and naturally cooled down to 80°C;

[0030] Add limestone water slurry with a solid content of 50% to the above slurry, react at a temperature of 60-65°C, and control the slag CaSO 4 The mass percentage content is 36.4%, stop adding limestone water slurry, add appropriate amount of H 2 O, pour out the slurry, filter with a vacuum pump, filter and separate the slurry, get 200ml H...

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Abstract

The invention discloses a method for preparing a manganese carbonate, ammonium sulfate and potassium sulfate compound fertilizer by using a Mn-containing residue in electrolytic MnO2 and electrolytic Mn production. The method comprises the steps of firstly weighing the Mn-containing residue, adding clear water and H2SO4 and carrying out temperature-programming reaction; and sectionally adding limestone, Ca(OH)2, NH4HCO3, (NH4)2CO3, K2CO3, KOH and H2SO4, controlling decomposition, transformation and synthesis reaction conditions, filtering, separating, purifying, evaporating, concentrating, crystallizing and drying a product to obtain MnCO3, CaSO4, (NH4)2SO4.H2SO4 and Si-Al gangue residues. According to the method, the Mn-containing residue for producing electrolytic MnO2 and electrolytic Mn can be completely recycled, three industrial waste emissions are avoided and resource utilization of the maximum extent is achieved.

Description

technical field [0001] The invention relates to the field of chemical technology, in particular to the treatment of electrolytic MnO 2 Manganese pollution of Mn-containing waste slag from electrolysis of Mn, environmental protection, recycling of manganese regeneration resources, preparation of manganese carbonate (MnCO 3 ) Ammonium sulfate potassium sulfate compound fertilizer ((NH 4 ) 2 SO 4 ·K 2 SO 4 ) of a method. Background technique [0002] Electrolytic MnO 2 It is mainly used in the production of dry batteries, and is used as the positive electrode material of alkaline manganese type, mercury-free alkaline manganese type, and lithium manganese type dry batteries. The production and export volume of dry batteries in my country rank first in the world. At present, my country's electrolytic MnO 2 The annual output is 260,000 tons. Due to the development of modern industry, especially the development of electronic industry, the electrolysis of MnO 2 The demand is...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01G45/00C05G1/10C01F11/46
CPCC01F11/46C01G45/00C05C3/00C05D1/02
Inventor 谭硕望连捷元周震宇唐海平刘春刚郭雯连广宇谭安国
Owner 湘潭市环境保护科学研究院
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