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A preparation method of textiles with formaldehyde elimination function

A formaldehyde elimination and textile technology, applied in textiles, papermaking, fiber processing, etc., can solve problems such as secondary pollution and damage to furniture

Active Publication Date: 2019-03-22
CHANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The chemical degradation method has the advantages of rapid formaldehyde elimination, high formaldehyde elimination rate, and less usage, but the spray type is easy to cause secondary pollution and may damage furniture
If the formaldehyde scavenger is treated on textiles and used as interior decoration textiles, it can effectively solve the problems of spray-type scavenger. At present, there are no similar reports on textiles with formaldehyde scavenging function.

Method used

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  • A preparation method of textiles with formaldehyde elimination function
  • A preparation method of textiles with formaldehyde elimination function

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Immerse the textile in a sodium periodate solution with a molar concentration of 2 mmol / L, react in the dark at 50°C for 45 minutes, then wash with deionized water three times, dry at 80°C, and set aside;

[0023] (2) Immerse 10 g of the textiles treated in step (1) into 100 mL of urea solution with a mass-volume concentration of 6 g / L, then react in a water bath at 30°C for 8 hours, filter, wash with deionized water for 3 times, and heat at 80°C dry, ready for use;

[0024] (3) adding the textiles processed through step (2) into the solution containing cobalt tetracarboxyphthalocyanine and leveling agent Pingping O, the mass-volume concentration of cobalt tetracarboxyphthalocyanine is 0.4g / L, and Pingping adding O The mass-volume concentration is 1g / L, the bath ratio is 1:50, the pH value is adjusted to 4, treated at 90°C for 90min, washed 3 times with water, and dried.

Embodiment 2

[0032] (1) Immerse the textile in a sodium periodate solution with a molar concentration of 8 mmol / L, react in the dark at 50°C for 30 minutes, then wash it with deionized water for 5 times, dry it at 100°C, and set aside;

[0033] (2) Immerse 10 g of the textiles treated in step (1) into 100 mL of urea solution with a mass-volume concentration of 10 g / L, then react in a water bath at 50°C for 4 hours, filter, wash with deionized water for 5 times, and wash at 100°C dry, ready for use;

[0034] (3) Add the textiles processed through step (2) into the solution containing cobalt octacarboxyphthalocyanine and leveling agent Pingping O, the mass-volume concentration of cobalt octacarboxyphthalocyanine is 0.8g / L, and the quality of Pingping O - The volume concentration is 3g / L, the bath ratio is 1:50, the pH value is adjusted to 7, and the treatment is carried out at 100°C for 30 minutes, washed 5 times with water, and then dried.

Embodiment 3

[0036] (1) Immerse the textile in a sodium periodate solution with a molar concentration of 6 mmol / L, react in the dark at 45°C for 35 minutes, then wash it with deionized water 4 times, dry it at 90°C, and set aside;

[0037] (2) Immerse 10 g of the textiles treated in step (1) into 100 mL of urea solution with a mass-volume concentration of 8 g / L, then react in a water bath at 40°C for 6 hours, filter, wash with deionized water 4 times, and place at 90°C dry, ready for use;

[0038] (3) adding the textiles processed through step (2) into the solution containing tetracarboxyphthalocyanine cobalt and leveling agent Pingping O, the tetracarboxyphthalocyanine cobalt mass-volume concentration is 0.6g / L, and the quality of Pingping O - The volume concentration is 2g / L, the bath ratio is 1:50, the pH value is adjusted to 6, and the treatment is carried out at 95°C for 60 minutes, washed 4 times with water, and then dried.

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Abstract

The invention provides a preparation method for a textile with a formaldehyde-removing function. The method comprises the following steps: firstly, selectively oxidizing a cellulosic fiber, thereby forming aldocellulose; utilizing Schiff base reaction between amido on urea and aldehyde group to generate an amido derivative; reacting the amido derivative with formaldehyde, thereby achieving the formaldehyde-removing function; and utilizing electrostatic attraction between amino and carboxyl to load metal phthalocyanine derivative onto the textile, wherein the metal phthalocyanine derivative has a function of catalytic degradation for formaldehyde.

Description

technical field [0001] The invention belongs to the technical field of textiles, in particular to a preparation method of textiles with formaldehyde elimination function. Background technique [0002] With the improvement of people's living standards, people's requirements for interior decoration standards are getting higher and higher, but the problem of indoor air chemical pollution caused by decoration also follows. Among many pollutants, formaldehyde is one of the main pollutants. Formaldehyde is extremely harmful to human health. Formaldehyde ranks second on the priority list of toxic chemicals in my country. It has been identified as a carcinogenic and teratogenic substance by the World Health Organization. It is a recognized source of allergies and one of the potential strong mutagens. one. Therefore, it is imperative to study feasible formaldehyde removal methods. [0003] Among the numerous indoor formaldehyde elimination methods, chemical degradation is an effect...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M11/30D06M13/432D06M15/53D06M13/503
CPCD06M11/30D06M13/432D06M13/503D06M15/53
Inventor 彭勇刚汪媛黎珊陶永新
Owner CHANGZHOU UNIV