Preparation method for perovskite solar cell with tetramino zinc phthalocyanine organic hole transmission layer

A technology of tetraaminozinc phthalocyanine and solar cells, which is applied in circuits, photovoltaic power generation, electrical components, etc., can solve pollution, and the production efficiency of perovskite solar cells is not high, which limits the production and application of perovskite solar cells and other issues to achieve the effects of reducing environmental pollution, improving photoelectric conversion efficiency, and reducing reaction time

Inactive Publication Date: 2016-07-06
SHANGHAI UNIV
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Problems solved by technology

However, the preparation efficiency of existing perovskite solar cells is not high, and there is a certain degre

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  • Preparation method for perovskite solar cell with tetramino zinc phthalocyanine organic hole transmission layer
  • Preparation method for perovskite solar cell with tetramino zinc phthalocyanine organic hole transmission layer
  • Preparation method for perovskite solar cell with tetramino zinc phthalocyanine organic hole transmission layer

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Embodiment Construction

[0021] Preferred embodiments of the present invention are described in detail as follows:

[0022] In this example, see Figure 1 to Figure 5 , a method for preparing a tetraaminozinc phthalocyanine organic hole transport layer perovskite solar cell, comprising the steps of:

[0023] 1) Preparation of tetraaminozinc phthalocyanine:

[0024]a. Preparation of tetranitrozinc phthalocyanine by microwave method: measure reactant raw material 4.03g zinc acetate, 21.11g4 -Nitrophthalic acid and 15g urea, then reactant raw material is mixed with the catalyzer tetrahydrate ammonium molybdate tetrahydrate of 0.2g to form reaction system material, after grinding evenly, then reaction system material is joined in the beaker of 500ml, then Put the beaker together with the materials of the reaction system in an oil bath at 140°C and stir for half an hour, then take the beaker out of the oil bath, and then put the beaker into a microwave oven. By adjusting the power of the microwave oven ...

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Abstract

The invention discloses a preparation method for a perovskite solar cell with a tetramino zinc phthalocyanine organic hole transmission layer. The preparation method comprises the following steps of preparing tetranitro zinc phthalocyanine by a microwave method; reducing the tetranitro zinc phthalocyanine to tetramino zinc phthalocyanine; and spin-coating a derivative serving as the organic hole transmission layer onto a TiO2 film coated with perovskite to prepare the perovskite solar cell. By the preparation method, a phthalocyanine derivative dye-tetramino zinc phthalocyanine is synthesized and is taken as the organic hole transmission layer of the perovskite TiO2 solar cell, the reaction time is greatly reduced with the adoption of microwave synthesis energy, the reaction yield is improved, and the environmental pollution is reduced; and moreover, the green, environmental-friendly and high-efficiency perovskite solar cell based on the hole transmission layer made of the organic material is prepared.

Description

technical field [0001] The invention relates to a preparation method of a solar cell, in particular to a perovskite type solar cell, which is applied in the field of solar cell preparation technology. Background technique [0002] At present, the manufacturing cost of silicon-based solar cells, which dominates the market, has been greatly reduced, which will ensure that the large-scale use of photovoltaic cells in the future will become inevitable. According to recent forecasts, between now and 2030, photovoltaic power generation will account for one-third of the world's new power generation capacity. However, if it has very high photoelectric conversion efficiency or low manufacturing cost, it has the opportunity to replace traditional solar cells and become the next generation of new high-efficiency solar cells. [0003] Recently, the new generation of mixed organic-inorganic lead halide perovskites (CH 3 NH 3 wxya 3 , X=Cl, Br, I), has these two characteristics, showi...

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Application Information

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IPC IPC(8): H01L51/48H01L51/46H01L51/44
CPCH10K85/311H10K30/80Y02E10/549Y02P70/50
Inventor 沈悦朱尧一陈祥皇甫民赞曹萌顾峰王林军
Owner SHANGHAI UNIV
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