adhesive sheet
A technology for adhesive sheets and wafers, applied in the direction of adhesives, film/sheet adhesives, synthetic resin layered products, etc., which can solve the problems of excessive softening of the intermediate layer, exudation of the intermediate layer, and absorption of bump height differences. , to achieve the effect of good embedding and preventing exudation
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Embodiment 1
[0161] (formation of middle layer)
[0162] 40 parts by mass (solid content ratio) of a bifunctional urethane acrylate oligomer (product name "CN9018", manufactured by Arkema Corporation, weight average molecular weight: 45,000) as a polyfunctional compound, and acrylic acid as a crystalline monomer 60 parts by mass of octaalkyl ester (STA) (solid content ratio), and 2,4,6-trimethylbenzoyl diphenylphosphine oxide (product name " DAROCUR TPO ", BASF company Production) 2.0 parts by mass (solid content ratio) were mixed to obtain a UV-curable composition for an intermediate layer. The composition for the intermediate layer was coated on a release film of polyethylene terephthalate (PET) film (product name "SP-PET381031", Lintec Co., Ltd. Co., Ltd., thickness 38 μm), a coating film was formed so that the thickness after curing was 200 μm.
[0163] Then, the coating film was cured by irradiating ultraviolet rays from the coating film side, and a substrate formed of a polyethylen...
Embodiment 2
[0168] As a multifunctional compound, a liquid butadiene polymer (product name "Ricon 154", manufactured by Crayvalley Co., Ltd., weight average molecular weight 5200) having a plurality of vinyl groups in the side chain was used, except that it was carried out in the same manner as in Example 1, An adhesive sheet was obtained.
Embodiment 3
[0170] As the polyfunctional compound, a bifunctional polyalkylacrylate (product name "RC100C", manufactured by Kaneka Co., Ltd., weight average molecular weight: 20,000) having polymerizable functional groups at both ends was used, except that it was the same as in Example 1. implemented.
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Abstract
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