Dimethylanthracene-containing organic compound and application thereof in organic electroluminescent devices
An organic compound, dimethyl anthracene technology, applied in the field of organic optoelectronic materials, can solve different problems and achieve the effects of improving current efficiency and life, improving exciton utilization rate, and good industrialization prospects
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Embodiment 1
[0051] The synthesis of embodiment 1 compound 1:
[0052]
[0053]
[0054] Add 11.8g of 1,4-dibromobenzene (0.05mol) and 1.33g of Mg powder (0.055mol) and 60ml of tetrahydrofuran to a 250ml four-necked flask under nitrogen atmosphere, heat and reflux for 4 hours, the reaction is complete, and the format Reagent;
[0055] Dissolve 11.1g of 10,10-dimethylanthrone (0.05mol) in 50ml of tetrahydrofuran, add the above-mentioned Grignard reagent dropwise, react at 60°C for 24 hours, a large amount of white precipitate is formed, and finally add saturated NHCl 4 Convert Grignard salt into alcohol; after the reaction, extract with ether, dry and rotary evaporate, petroleum ether: dichloromethane mixed solvent (3:2) silica gel column purification to obtain a slightly yellow solid tertiary alcohol (yield 88%) ; using DEI-MS to identify the compound, formula C 22 h 19 BrO, detection value [M+1] + = 379.03, calculated value 378.06;
[0056] Take 15.2g of the above-mentioned ter...
Embodiment 2
[0059] The synthesis of embodiment 2 compound 3:
[0060]
[0061] synthetic route:
[0062]
[0063] Prepared according to the synthetic method of compound 1 in Example 1, the difference is that compound B is replaced by compound C;
[0064] Using DEI-MS to identify the compound, formula C 49 h 40 N 2 , detection value [M+1] + =657.13, calculated value 656.32.
Embodiment 3
[0065] The synthesis of embodiment 3 compound 15:
[0066]
[0067] synthetic route:
[0068]
[0069] Prepared according to the synthetic method of compound 1 in Example 1, the difference is that compound B is replaced by compound D;
[0070] Using DEI-MS to identify the compound, formula C 49 h 39 NO, detection value [M+1] + =658.15, calculated value 657.30.
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