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Preparation of a gasoline scrubbing resistant PBT material

A gasoline and PBT resin-resistant technology, which is applied in the field of polybutylene terephthalate (PBT) plastics, can solve the problems of not being resistant to gasoline scrubbing, product scrapping, and difficult to be identified, achieving fewer processes and lower costs , the effect of simple preparation method

Active Publication Date: 2019-05-28
绍兴市聚成新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the content printed by ink printing in some application places (auto repair) is not resistant to gasoline scrubbing, so the technical parameters of the product are easy to be wiped off and difficult to be identified, resulting in product scrapping

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A gasoline scrubbing-resistant PBT material, the composition of which is calculated in parts by mass:

[0028] PBT resin 79.8

[0029] epoxy resin 15

[0030] Polyvinyl alcohol 1.0

[0031] Toughener 3.0

[0032] Antioxidant 0.4

[0033] PETS 0.3

[0034] Coupling agent 0.5

[0035] Stir the PBT resin, powder epoxy resin, polyvinyl alcohol, silane coupling agent, toughening agent, antioxidant, PETS and dried pearl powder at a stirring speed of 2000 r / min and a stirring time of 3 min. The mixed raw materials are added to the hopper, extruded and granulated through a twin-screw extruder, the extrusion temperature is 235-250 ° C, and the screw speed is 400-450 r / min, that is, the gasoline scrub resistant PBT material is obtained.

Embodiment 2

[0037] A gasoline scrubbing-resistant PBT material, the composition of which is calculated in parts by mass:

[0038] PBT resin 72.8

[0039] epoxy resin 20

[0040] Polyvinyl alcohol 3.0

[0041] Toughener 3.0

[0042] Antioxidant 0.4

[0043] PETS 0.3

[0044] Coupling agent 0.5

[0045] Stir the PBT resin, powder epoxy resin, polyvinyl alcohol, silane coupling agent, toughening agent, antioxidant, PETS and dried pearl powder at a stirring speed of 2000 r / min and a stirring time of 3 min. The mixed raw materials are added to the hopper, extruded and granulated through a twin-screw extruder, the extrusion temperature is 235-250 ° C, and the screw speed is 400-450 r / min, that is, the gasoline scrub resistant PBT material is obtained.

Embodiment 3

[0047] A gasoline scrubbing-resistant PBT material, the composition of which is calculated in parts by mass:

[0048] PBT resin 65.8

[0049] epoxy resin 25

[0050] Polyvinyl alcohol 5.0

[0051] Toughener 3.0

[0052] Antioxidant 0.4

[0053] PETS 0.3

[0054] Coupling agent 0.5

[0055] Stir the PBT resin, powder epoxy resin, polyvinyl alcohol, silane coupling agent, toughening agent, antioxidant, PETS and dried pearl powder at a stirring speed of 2000 r / min and a stirring time of 3 min. The mixed raw materials are added to the hopper, extruded and granulated through a twin-screw extruder, the extrusion temperature is 235-250 ° C, and the screw speed is 400-450 r / min, that is, the gasoline scrub resistant PBT material is obtained.

[0056] Table 1

[0057]

[0058] The material properties of Examples 1 to 3 are shown in Table 1. It can be seen from the table that the PBT plastic prepared according to the above formula and process, with the increase of the c...

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PUM

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Abstract

The invention relates to a gasoline scrubbing-resistant PBT (polybutylene terephthalate) material. The gasoline scrubbing-resistant PBT material is prepared from the following components in parts by mass: 64 to 82.9 parts of PBT resin, 15 to 25 parts of epoxy resin, 1.0 to 5.0 parts of polyvinyl alcohol, 0.5 to 3.0 parts of toughener, 0.2 to 1.0 part of antioxidant, 0.2 to 0.5 part of PETS, and 0.2 to 1.5 parts of coupling agent, wherein the PBT resin is milky white, and the characteristic viscosity is 0.7 to 0.8dl / g; the toughener is a POE-g-GMA and POE-g-MAH compound; an adhesive additive is a powdery epoxy resin and polyvinyl alcohol compound; the coupling agent is aminopropyltriethoxysilane. A preparation method of the low temperature impact-resistant PBT material with spraying-free and pearl effect comprises the following steps of stirring the PBT resin, the powdery epoxy resin, the polyvinyl alcohol, the silane coupling agent, the toughener, the antioxidant, the PETS and the dried pearl powder for 3min at the stirring speed of 2000r / min; adding the mixed raw materials into a material hopper, and enabling a double-screw extruder to extrude and granulate, wherein the extrusion temperature is 235 to 250 DEG C, and the rotation speed of each screw is 400 to 450r / min, so as to obtain the gasoline scrubbing-resistant PBT material.

Description

technical field [0001] The invention relates to the technical field of modification of polybutylene terephthalate (PBT) plastics, in particular to a polybutylene terephthalate (PBT) plastic that can be resistant to gasoline scrubbing. Background technique [0002] Polybutylene terephthalate (PBT) is an engineering plastic with good dimensional stability, fast crystallization, excellent electrical properties and chemical resistance. Because of the above characteristics, it is widely used in electrical and electronic, auto parts and office supplies parts. [0003] Products prepared from existing PBT materials (such as office supplies and auto parts) need to indicate the model of the product and some technical parameters after production is completed, and inkjet printing will be used on the surface of the product. However, the content printed in some application places (automobile repair) by ink printing is not resistant to gasoline scrubbing, so the technical parameters of th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L63/00C08L29/04C08L51/06C08K5/544
CPCC08L67/02C08L2205/035C08L63/00C08L29/04C08L51/06C08K5/544
Inventor 杨建江宋利园
Owner 绍兴市聚成新材料科技股份有限公司