Mothproof and mildewproof material for finance management cabinet and preparation method thereof
A moth-proof, mildew-proof and management cabinet technology is applied in the field of financial management appliances, which can solve the problems that financial management cabinets cannot be mould-proof, column-proof and moisture-proof at the same time. Effect
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Embodiment 1
[0024] A method for preparing a moth-proof and mildew-proof material for a financial management cabinet, comprising the following steps:
[0025] 1) Chitosan quaternization: add chitosan 100g and bromopropane 250g to isopropanol 2000g in proportion, stir and react at room temperature for 4 hours, then precipitate in ether and wash 3 times with isopropanol , and finally place the product in a vacuum drying oven at a temperature of 90°C for 24 hours;
[0026] 2) Ion exchange: Soak the quaternized chitosan prepared in step 1) in an aqueous solution of sodium pentachlorophenate with a mass fraction of 10% at 60°C for 52 hours, and then soak it in water for 2 hours, take it out and place it in a vacuum drying oven to dry at 90°C for 24 hours;
[0027] 3) Preparation of quaternized chitosan grafted acrylonitrile hydrolyzate: Under the protection of nitrogen, 50 g of the ion-exchanged quaternized chitosan prepared in step 2) was added to 1000 g of water, and heated at 80 ° C Stir a...
Embodiment 2
[0032] A method for preparing a moth-proof and mildew-proof material for a financial management cabinet, comprising the following steps:
[0033] 1) Chitosan quaternization: add chitosan 100g and bromopropane 260g to isopropanol 3000g in proportion, stir and react at room temperature for 5 hours, then precipitate in ether and wash 4 times with isopropanol , and finally place the product in a vacuum drying oven at a temperature of 95°C for 25 hours;
[0034] 2) Ion exchange: Soak the quaternized chitosan prepared in step 1) in an aqueous solution of sodium pentachlorophenate with a mass fraction of 15% at 65°C for 60 hours, and then soak it in water for 2.5 hours, take it out and place it in a vacuum oven to dry at 95°C for 27 hours;
[0035] 3) Preparation of quaternized chitosan grafted acrylonitrile hydrolyzate: Under the protection of argon, 50 g of the ion-exchanged quaternized chitosan prepared in step 2) was added to 1000 g of water, at 82 Stir at ℃ for 57 minutes, the...
Embodiment 3
[0040] A method for preparing a moth-proof and mildew-proof material for a financial management cabinet, comprising the following steps:
[0041] 1) Chitosan quaternization: add chitosan 100g and bromopropane 280g to isopropanol 4500g in proportion, stir and react at room temperature for 6 hours, then precipitate in ether and wash 5 times with isopropanol , and finally place the product in a vacuum drying oven at a temperature of 96°C for 27 hours;
[0042] 2) Ion exchange: soak the quaternized chitosan prepared in step 1) in an aqueous solution of sodium pentachlorophenate with a mass fraction of 17% at 67°C for 62 hours, and then soak it in water for 2.7 hours, take it out and place it in a vacuum oven to dry at 97°C for 28 hours;
[0043] 3) Preparation of quaternized chitosan grafted acrylonitrile hydrolyzate: Under the protection of neon gas, 50 g of the ion-exchanged quaternized chitosan prepared in step 2) was added to 1000 g of water, at 83 Stir at ℃ for 65 minutes, th...
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