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Integrated device for catalytic-cracking-flue-gas desulfurization, denitration, dust removing and acid mist removing and method

A catalytic cracking, desulfurization and denitrification technology, applied in chemical instruments and methods, combined devices, gas treatment, etc., can solve problems such as non-compliance with emission standards, nitrogen oxides failing to meet technical guarantee value indicators, and soot concentration failing to meet emission standards, etc. , to achieve the effect of solving tailing and improving desulfurization efficiency

Pending Publication Date: 2018-04-24
ASIA PACIFIC ENVIRONMENTAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Existing catalytic cracking flue gas is mostly treated by foreign sodium method. A petrochemical catalytic cracking flue gas adopts the EDV+LoTOX process technology of BELCO company in the United States, and the dust concentration after treatment is 86-130mg / Nm 3 , nitrogen oxides 164-191mg / Nm 3 , sulfur dioxide at 20mg / Nm 3 Below, the concentration of smoke and dust cannot meet the requirements of emission standards, and the nitrogen oxides cannot meet the technical guarantee value indicators; the concentration of sulfuric acid mist at the outlet is 65-84mg / Nm 3 , within the concentration range where smoke plume is easy to form, does not meet the existing emission standards

Method used

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  • Integrated device for catalytic-cracking-flue-gas desulfurization, denitration, dust removing and acid mist removing and method
  • Integrated device for catalytic-cracking-flue-gas desulfurization, denitration, dust removing and acid mist removing and method
  • Integrated device for catalytic-cracking-flue-gas desulfurization, denitration, dust removing and acid mist removing and method

Examples

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Effect test

Embodiment 1

[0030] like figure 1 As shown, an integrated device for catalytic cracking flue gas desulfurization, denitration, dust removal and acid mist removal includes an ozone generator 2 and a desulfurization tower 4; the desulfurization tower 4 is provided with an inclined flue 11 and a chimney 7, and the inclined flue 11 and the chimney 7, according to the flue gas flow direction in the desulfurization tower 4, the quenching spray pipe 18, the ozone gas distribution plate 19, the accident spray pipe 13, the first air lift cap 12, several empty tower spray pipes 14, the first The two-liter air cap 15, the ammonia demister 16, the roof ridge demister 17 and the wire mesh demister 10; the ozone generator 2 is communicated with the ozone air distribution plate 19 through a pipeline.

[0031] like figure 2 As shown, the acid mist content of the flue gas at the inlet of the wire mesh demister 10 is > 70 mg / Nm 3 , the wire mesh demister 10 is replaced with an electric demister 25.

[0...

Embodiment 2

[0059] A method for treating flue gas from catalytic cracking using the device of Example 1, comprising the following steps: flue gas with a temperature ≤ 200°C and a humidity of 7% to 10% from the waste heat boiler of the catalytic cracking unit, the concentration of sulfur dioxide in the flue gas is between 1000~2000mg / Nm 3 、NOx content 100~350mg / Nm 3 And the concentration of catalyst dust is 30~600mg / Nm 3 The flue gas is cooled through the quenching spray pipe 18, and then the ozone desulfurization is carried out through the ozone gas distribution pan 19, and then through the accident spray pipe 13, the first gas-raising cap 12, several empty tower spray pipes 14, the second gas-raising Cap 15, ammonia demister 16, roof ridge demister 17 and wire mesh demister 10 or electric demister 25 remove ammonia mist, water mist and sulfuric acid mist.

[0060] Specifically, the reaction contact time of the flue gas for ozone desulfurization is 1 to 2 seconds, the ammonia demister 1...

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Abstract

The invention discloses an integrated device for catalytic-cracking-flue-gas desulfurization, denitration, dust removing and acid mist removing. The integrated device comprises an ozone generator anda desulfurization tower; a slant flue and a chimney are arranged on the desulfurization tower, and a rapid-cooling spraying pipe, an ozone distribution disc, an accident spraying pipe, a first riser cap, a plurality of empty tower spraying pipes, a second riser cap, an ammonia demister, a ridge demister and a mesh demister are sequentially arranged at the portion, between the slant flue and the chimney, in the desulfurization tower in the flue-gas flowing direction; the ozone generator is communicated with the ozone distribution disc through a pipe. The integrated device has the advantages that the desulphurization efficiency of flue gas can be effectively improved, generation of ammonia escaping, aerosol and acid mist can be effectively controlled, and meanwhile both Sox and NOx enter thefollow-up working procedure. Dust in the flue gas is removed through a flue gas-dust separating device, the desulfurization rate of the device is larger than or equal to 99%, the denitration rate islarger than or equal to 60%, the dust removing rate is larger than or equal to 80%, the removing rate of acid mist is larger than or equal to 90% when mist is removed with electricity, and the removing rate of the acid mist is larger than or equal to 60% when mist is removed with screen meshes.

Description

technical field [0001] The invention belongs to the technical field of environmental protection, and in particular relates to an integrated device and method for desulfurization, denitrification, dust removal, acid mist removal and acid mist removal of catalytic cracking flue gas. Background technique [0002] In recent years, a large amount of regenerator flue gas has become an important source of air pollution because it contains a large amount of SOx, NOx, particulate matter, acid mist and CO. It is estimated that SOx emissions from refineries account for about 6% to 7% of their total emissions, while SOx emissions from catalytic cracking account for about 5%. The pressure of the environmental situation has made the pressure of catalytic cracking pollutant emissions continue to increase. [0003] At present, the wet flue gas desulfurization processes of catalytic cracking units include the EDvD process of BELCO Company of the United States, the EP-Absorber process of GEA...

Claims

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Application Information

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IPC IPC(8): B01D53/75B01D53/76B01D53/78B01D53/79B01D50/00B01D53/50B01D53/56
CPCB01D50/00B01D53/504B01D53/56B01D53/75B01D53/76B01D53/78B01D53/79B01D2251/104B01D2258/0283
Inventor 曾子平刘应隆张翠
Owner ASIA PACIFIC ENVIRONMENTAL CORP
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