Preparing method of improved melamine resin essence microcapsule finishing agent

A technology of essence microcapsules and melamine resin, which is applied in the direction of microcapsule preparation, microsphere preparation, fiber treatment, etc. It can solve the problems of short fragrance retention time, low fragrance encapsulation rate, and low mechanical strength of capsule wall, etc., and achieves good results. , The effect of simplifying the finishing process

Inactive Publication Date: 2018-05-08
贺州宝兴新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional microcapsule technology usually uses physical methods to prepare various open-cell flavor microcapsules, and then uses adhesives and crosslinking agents to mechanically adhere the microcapsules to fabric fibers, and the fragrance retention time is not long; at the same time Due to the existence of the adhesive, the hand feeling is not good, which affects the comfort when wearing
[0004] However, the fragrance microcapsules sold on the market today often have disadvantages such as low packaging rate of fragrance, low mechanical strength of the capsule wall, short fragrance retention time, low affinity with fabric fibers, and difficult bonding.

Method used

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Examples

Experimental program
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preparation example Construction

[0024] A preparation method of a modified melamine resin essence microcapsule finishing agent, comprising the steps of:

[0025] (1) Preparation of styrene-maleic anhydride copolymer powder

[0026] Dissolve 5.4g of azobisisobutyronitrile in 60.0kg of 3-hexanone to form reaction solution A; 25.8kg of maleic anhydride and 82.3kg of styrene are mixed and dissolved to form reaction solution B;

[0027] The reaction medium in the reaction kettle is 103.5kg of 3-hexanone, the temperature of the reaction medium in the reaction kettle is controlled at 70°C by an oil bath, and the reaction solution A and the reaction solution B are respectively fed into the reaction continuously at a low price through different pipelines. Reactor, after the low price, react for 2 hours to end the reaction, increase the temperature, and distill 3-hexanone under reduced pressure, discharge the material from the reactor after melting, obtain a solid after cooling, and grind it into powder;

[0028] (2) ...

Embodiment 1

[0038] (1) Preparation of styrene-maleic anhydride copolymer powder

[0039] Dissolve 5.4g of azobisisobutyronitrile in 60.0kg of 3-hexanone to form reaction solution A; 25.8kg of maleic anhydride and 82.3kg of styrene are mixed and dissolved to form reaction solution B;

[0040]The reaction medium in the reaction kettle is 103.5kg of 3-hexanone, the temperature of the reaction medium in the reaction kettle is controlled at 70°C by an oil bath, and the reaction solution A and the reaction solution B are respectively fed into the reaction continuously at a low price through different pipelines. Reactor, after the low price, react for 2 hours to end the reaction, increase the temperature, and distill 3-hexanone under reduced pressure, discharge the material from the reactor after melting, obtain a solid after cooling, and grind it into powder;

[0041] (2) Preparation of styrene-maleic anhydride copolymer solution

[0042] Add 1 part of styrene-maleic anhydride copolymer powder...

Embodiment 2

[0051] (1) Preparation of styrene-maleic anhydride copolymer powder

[0052] The solution medium added to the reactor is 300kg of toluene, an oil bath, and the temperature is 90°C. The molar ratio of MAH and St is 1:1, wherein 38.812kg of maleic anhydride, 41.188kg of styrene, and 4kg of azobisisobutyronitrile (AIBN) as the initiator are dissolved and mixed with solvent trimethylbenzene 120kg and butanone 39kg to obtain a mixed solution . The mixed solution was added dropwise into the reactor for 4 hours, and the reaction was continued for 1 hour after the dropwise addition. Filtrate and dry to obtain styrene-maleic anhydride copolymer powder with a weight average molecular weight of 6635kg / mol.

[0053] (2) Preparation of styrene-maleic anhydride copolymer solution

[0054] Add 3 parts of styrene-maleic anhydride copolymer powder and 17 parts of deionized water into the four-necked bottle by weight, heat up to 85°C under stirring conditions, and adjust the pH to 10,5 with ...

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Abstract

The invention discloses a preparing method of an improved melamine resin essence microcapsule finishing agent. The method includes the step of encapsulating essence through an in-situ polymerization method and an interface polymerization method with styrene-maleic anhydride copolymer as the emulsifying agent, essence as the capsule core and melamine resin and polyacrylate as the wall materials toprepare melamine resin essence microcapsules. The self-adhesive double-wall essence microcapsules prepared through the safe and environment-friendly preparing method have the solid content of 35-38% which is 10-15% higher than the solid content of other essence microcapsules on the market. Dual-layer wall constructing is conducted through the in-situ polymerization method and the interface polymerization method, the essence wrapping rate can reach 91-95%, and the product emulsion has high stability. The self-adhesive double-wall essence microcapsules have the unique advantages of microcapsulesand have self-adhesion performance, and the cotton fabric finishing process is simplified. The finished cotton fabric has a good fragrance depositing effect, the standing fragrance depositing time can reach 8 months, and the cotton fabric can still keep the pleasant fragrance after being washed with water 12 times.

Description

technical field [0001] The invention belongs to the technical field of textile finishing, and in particular relates to a modified melamine resin essence microcapsule finishing agent prepared by in-situ polymerization, with low methyl etherified melamine resin as the wall material and essence as the core material. Preparation. Background technique [0002] With the development of the economy and the improvement of living standards, people's requirements for textiles have undergone great changes. From the past practical type to the decoration, enjoyment, and health care type, textile perfuming conforms to this trend. Because scented textiles have the functions of antibacterial and insect repellent, covering peculiar smell, and making body and mind comfortable, they are generally liked by people. In ancient my country, there was the habit of sewing sachets on clothes; Europe has sprayed perfume on clothes since the Middle Ages as an elegant style, and later, there was a method...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M23/12D06M13/00D06M15/233D06M15/263D06M15/423D06M15/31C08F212/08C08G12/32C08F220/14C08F220/48C08F220/18C08F220/06C08F220/20C08F220/58B01J13/18B01J13/16D06M101/06
CPCB01J13/16B01J13/185C08F212/08C08F220/14C08F220/48C08G12/32D06M13/005D06M15/233D06M15/263D06M15/31D06M15/423D06M23/12D06M2101/06C08F222/06C08F220/1804C08F220/1808C08F220/06C08F220/20C08F220/58
Inventor 张万龙
Owner 贺州宝兴新材料股份有限公司
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