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A kind of micro-emulsion of magnesium alloy plate strip medium temperature rolling and preparation method thereof

A technology of magnesium alloy plates and microemulsions, applied in lubricating compositions, petroleum industry, etc., can solve problems such as easy fire, poor surface cleanliness, poor lubrication performance of emulsion, etc., to achieve improved safety, excellent lubrication performance, easy The effect of storage and transportation

Active Publication Date: 2019-06-21
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Pure oil-based lubricants have the problems of being easy to catch fire and have poor surface cleanliness, while emulsions have poor lubricating properties

Method used

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  • A kind of micro-emulsion of magnesium alloy plate strip medium temperature rolling and preparation method thereof
  • A kind of micro-emulsion of magnesium alloy plate strip medium temperature rolling and preparation method thereof
  • A kind of micro-emulsion of magnesium alloy plate strip medium temperature rolling and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1 concrete each component formula is as shown in table 2.

[0015] serial number Component chemical name mass (g) 1 D130 25.00 2 Calcium chloride aqueous solution (0.02mol / L) 34.00 3 Oleic acid 6.00 4 Triethanolamine 1.50 5 Sorbitan Fatty Acid Ester 10.00 6 polyethylene glycol 400 6.00 7 Sodium petroleum sulfonate 8.00 8 n-propanol 9.00 9 dialkyl dithiophosphate 0.5

[0016] (1) Weigh the surfactant SPAN80 according to the above formula, add sodium petroleum sulfonate, PEG400, oleic acid and triethanolamine into D130 and stir evenly, then add co-surfactant n-propanol and extreme pressure agent dialkyldithio Phosphate ester, stir evenly again, heat to 40-50°C and keep it still to remove air bubbles, then cool to room temperature to finally obtain a stable oil phase.

[0017] (2) Weigh 0.01 mol of anhydrous calcium chloride and dissolve it in 500 ml of deionized water to obtain a cal...

Embodiment 2

[0020] Embodiment 2 concrete each component formula is as shown in table 3.

[0021]

[0022]

[0023] (1) Weigh the surfactant SPAN80 according to the above formula, add sodium petroleum sulfonate, PEG400, oleic acid and triethanolamine into D130 and stir evenly, then add co-surfactant n-propanol and extreme pressure agent dialkyldithio Phosphate ester, stir evenly again, heat to 40-50°C and keep it still to remove air bubbles, then cool to room temperature to finally obtain a stable oil phase.

[0024] (2) Weigh 0.01 mol of anhydrous calcium chloride and dissolve it in 500 ml of deionized water to obtain a calcium chloride electrolyte solution with a concentration of 0.02 mol / L.

[0025] (3) Slowly add the calcium chloride electrolyte solution prepared above into the oil phase, and stir rapidly while adding, and after the mixed solution turns from turbid to clear and transparent at the beginning, a microemulsion of the magnesium alloy plate and strip is obtained at med...

Embodiment 3

[0027] Embodiment 3 concrete each component formula is as shown in table 4.

[0028]

[0029]

[0030] (1) Weigh the surfactant SPAN80 according to the above formula, add sodium petroleum sulfonate, PEG400, oleic acid and triethanolamine into D130 and stir evenly, then add co-surfactant n-propanol and extreme pressure agent dialkyldithio Phosphate ester, stir evenly again, heat to 40-50°C and keep it still to remove air bubbles, then cool to room temperature to finally obtain a stable oil phase.

[0031] (2) Weigh 0.01 mol of anhydrous calcium chloride and dissolve it in 500 ml of deionized water to obtain a calcium chloride electrolyte solution with a concentration of 0.02 mol / L.

[0032] (3) Slowly add the calcium chloride solution prepared above into the oil phase, stir rapidly while adding, and wait for the mixed solution to become clear and transparent from the initial turbidity, and then obtain the microemulsion of the magnesium alloy strip for medium-temperature r...

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Abstract

The invention belongs to the field of metal processing lubricants and relates to middle-temperature rolling micro-emulsion of a magnesium alloy sheet strip and a preparation method of the middle-temperature rolling micro-emulsion. High-flash-point aromatic hydrocarbon removing type solvent oil D130 is used as basic oil, and sorbitan fatty acid ester (SPAN80), polyethylene glycol 400 (PEG 400), sodium petroleum sulfonate, oleic acid and triethanolamine are used as a compound surfactant; n-propyl alcohol is used as a co-surfactant; dialkyl dithiophosphate is used as an extreme-pressure agent; awater solution of calcium chloride is used as electrolyte. The moisture content of the micro-emulsion can reach 28 percent to 35 percent and is not layered when the micro-emulsion is centrifuged at ahigh speed of 800r / min; the micro-emulsion is uniformly dispersed and is stable for a long period; the micro-emulsion is easy to store and transport, and a condition that a lot of unstable emulsifiedliquid is directly transported by a manufacturer is avoided and the safety of transportation is effectively improved. The micro-emulsion can be directly used in a middle-temperature rolling process ofthe magnesium alloy sheet strip, and has the characteristics of good lubricating performance and cleaning performance.

Description

technical field [0001] The invention relates to a lubricant for metal processing, which is used as a lubricant and a coolant in the medium-temperature rolling process of magnesium alloy strips, in particular to a microemulsion for medium-temperature rolling of magnesium alloy strips and a preparation method thereof. Background technique [0002] As the lightest structural material currently available in engineering, magnesium alloy has good shock absorption and is easier to recycle compared with plastics. It is known as "21st century green engineering material" and is widely used in aviation, aerospace, transportation Tools, 3C products, etc. Cast magnesium alloys have coarse grains, severe segregation, and are prone to defects, which greatly limit the application range of magnesium alloys. Plastic processing (such as forging, extrusion and rolling, etc.) can effectively improve the microstructure of magnesium alloys, eliminate casting defects, and improve the mechanical pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10M173/00C10N40/24C10N50/00C10N30/06C10N30/04
CPCC10M173/00C10M2201/06C10M2207/021C10M2207/126C10M2207/283C10M2209/104C10M2215/042C10M2219/044C10M2223/047C10N2030/04C10N2030/06C10N2040/24C10N2050/013C10N2010/02C10N2010/04
Inventor 孙建林董唱严旭东程紫旋
Owner UNIV OF SCI & TECH BEIJING