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Preparation method of high-gloss extinction electrophoretic coating

A high-gloss, photoelectric technology, applied in the field of coatings, can solve the problems of uneven paint film, low gloss, poor stability, etc., and achieve the effect of high gloss, good paint film flatness and good stability

Active Publication Date: 2018-08-31
江阴恒兴涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing electrophoretic coating, after adding matting agent, its gloss can reach low gloss (60 degree gloss meter measured less than or equal to 10 degrees), but its stability is poor, 3-5 months of storage will appear delamination phenomenon, and After use, the paint film is uneven and not delicate

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Embodiment 1. A high-gloss matting electrophoretic coating, the mass ratio of acrylic resin and amino resin in the main material is 1:0.5; wherein:

[0037] Acrylic resin is prepared from the following raw materials in mass fractions: 3 parts of isooctyl methacrylate, 8 parts of n-butyl acrylate, 7 parts of methyl methacrylate, 2 parts of styrene, 3 parts of acrylic acid, 2- 0.5 parts of hydroxyethyl ester, 1 part of 2-hydroxyethyl acrylate, 1 part of 2-hydroxypropyl acrylate, 1 part of polycarbonate (the number average molecular weight is 8000), 0.1 part of dinonylnaphthalenesulfonic acid, 0.5 parts of composite initiator Parts (azobisisobutylcyanide and DCP (dicumyl peroxide) according to 1:3), triethanolamine neutralizer 1 part, defoamer 0.01 part, n-butanol 10 parts, isopropanol 10 parts and 30 parts of deionized water. Its preparation method is as follows:

[0038] Step 1. Configure the mixed solution

[0039] Isooctyl methacrylate, n-butyl acrylate, methyl meth...

Embodiment 2

[0051] Embodiment 2, a kind of high-gloss matting electrophoretic coating, described acrylic resin is prepared by the raw material of following mass fraction: 4 parts of isooctyl methacrylate, 8 parts of n-butyl acrylate, 6 parts of methyl methacrylate , 3 parts of styrene, 4 parts of acrylic acid, 0.3 parts of 2-hydroxyethyl methacrylate, 1.5 parts of 2-hydroxyethyl acrylate, 1 part of 2-hydroxypropyl acrylate, 1 part of polycarbonate (the number average molecular weight is 5000 ), 0.15 parts of dinonyl naphthalene sulfonic acid, 0.8 parts of composite initiator (azobisisobutylcyanide and DCP (dicumyl peroxide) according to 1:3), 1.2 parts of triethanolamine neutralizer, disinfectant 0.01 parts of foaming agent, 10 parts of n-butanol, 10 parts of isopropanol and 30 parts of deionized water.

[0052] All the other are the same with embodiment 1.

Embodiment 3

[0053] Embodiment 3, a kind of high-gloss matte electrophoretic coating, described acrylic resin is prepared by the raw material of following mass fraction: 3.5 parts of isooctyl methacrylate, 9 parts of n-butyl acrylate, 8 parts of methyl methacrylate , 2 parts of styrene, 4 parts of acrylic acid, 0.4 parts of 2-hydroxyethyl methacrylate, 1 part of 2-hydroxyethyl acrylate, 1 part of 2-hydroxypropyl acrylate, 1 part of polycarbonate (the number average molecular weight is 5000 ), 0.05 parts of dinonyl naphthalene sulfonic acid, 0.5 parts of composite initiator (azobisisobutylcyanide and DCP (dicumyl peroxide) according to the ratio of 1:2), 1.5 parts of methyldiethanolamine neutralizer , 0.02 parts of defoamer, 15 parts of n-butanol, 15 parts of isopropanol and 40 parts of deionized water.

[0054] All the other are the same with embodiment 1.

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PUM

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Abstract

The invention relates to a preparation method of a high-gloss extinction electrophoretic coating comprising acrylic resin and amino resin; the mass ratio of acrylic resin to amino resin is 1 to (0.2-1), and the acrylic resin is prepared from the following raw materials in parts by mass: 3-4 parts of isooctyl methacrylate, 6-9 parts of n-butyl acrylate, 5-8 parts of methyl methacrylate, 1-3 parts of styrene, 2-4 parts of acrylic acid, 0.1-0.5 part of 2-hydroxyethyl methacrylate, 1-2 parts of 2-hydroxyethyl acrylate, 1-2 parts of 2-hydroxypropyl acrylate, 0.5-1 part of polycarbonate, 0.05-0.3 part of dinonylnaphthalene sulfonic acid, 0.5-1 part of a compound initiator, 1-2 parts of a neutralizer, 0.01-0.02 part of a defoamer, 8-15 parts of n-butanol, 8-15 parts of isopropanol and 10-50 partsof deionized water; the number-average molecular weight of the polycarbonate is 5000-10000. The finally prepared electrophoretic coating has good extinction effect (the gloss degree of greater than 70 degrees and less than 80 degrees is detected by a 60-degree gloss meter), and has no stratification phenomenon and good stability after being stored for one year or more; and a paint film is good insmoothness, strong in anti-pollution ability, easy to use and good in adhesive force to a used substrate.

Description

technical field [0001] The invention relates to a preparation method of a high-gloss matte electrophoretic coating, which belongs to the technical field of coatings. Background technique [0002] Electrophoresis is one of the most effective methods of coating metal workpieces. Electrophoretic coating is a new type of coating with low pollution, energy saving, resource saving and good corrosion resistance. It has the advantages of smooth coating film, good water resistance and chemical resistance, and it is easy to realize the mechanization and automation of the coating industry. It is suitable for the coating of workpieces with complex shapes, edges, corners, and holes. It is widely used in the coating of hardware such as automobiles, automatic vehicles, electromechanical appliances, and home appliances. [0003] In order to obtain a matting effect, one way is to add matting agents, such as silicon oxide, organic microparticles, etc., to the coating. However, the chemical ...

Claims

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Application Information

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IPC IPC(8): C09D133/08C09D133/12C09D161/32C09D5/44C09D7/63C09D7/65C09D7/62C08F220/18C08F220/14C08F212/08C08F220/06C08F220/20
CPCC08F212/08C08F220/06C08F220/14C08F220/18C08F220/1804C08F220/20C09D5/4411C09D5/4469C09D5/4473C09D5/448C08F220/1808
Inventor 葛丽珠林乾隆
Owner 江阴恒兴涂料有限公司
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