Nonaqueous electrolyte solution for secondary battery, and secondary battery provided with said solution
A non-aqueous electrolyte and secondary battery technology, applied in the direction of non-aqueous electrolyte batteries, secondary batteries, non-aqueous electrolytes, etc., can solve the problems of not showing cycle characteristics, achieve excellent cycle characteristics, and improve cycle characteristics
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Embodiment 1
[0267]
[0268] In an argon atmosphere drying oven with a dew point below -70°C, it is prepared relative to a mixed solvent composed of ethylene carbonate (EC) and dimethyl carbonate (DMC) (the volume ratio is EC:DMC=1:1 , manufactured by Kishida Chemical Co., Ltd., lithium battery grade), LiPF 6 The concentration is 1.0 mol / L.
[0269] Next, the above-mentioned ethyl lithium monofluorophosphate was added to the above-mentioned mixed solvent at a concentration of 0.5% by mass relative to the total mass of the non-aqueous electrolytic solution. Thus, the non-aqueous electrolytic solution according to the present example was prepared.
Embodiment 2
[0271] In this embodiment, as an additive, lithium bisoxalate borate is added to the above mixed solvent, and the added concentration is 0.5% by mass relative to the total mass of the non-aqueous electrolytic solution. Other than that, the non-aqueous electrolytic solution according to this example was prepared in the same manner as in Example 1 above.
Embodiment 3
[0273] In this example, instead of lithium bisoxalate borate in Example 2, vinylene carbonate was added at a concentration of 0.5% by mass. Except for this, the nonaqueous electrolytic solution of this example was prepared in the same manner as in Example 2.
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