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A kind of organic reinforcement material for mining and preparation method thereof

A reinforcement material and organic technology, which is applied in the field of organic reinforcement materials for mines and its preparation, can solve problems such as brittleness that cannot be widely recognized, large material reaction heat release, and many safety production accidents, and achieve excellent mechanical properties and reaction heat release. Low, good fluidity effect

Active Publication Date: 2021-03-30
山西凝固力新型材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although urea-formaldehyde and phenolic reinforcement materials have the advantages of good permeability, adjustable gel speed, and low cost, their disadvantages such as low strength and brittleness prevent them from being widely recognized.
Polyurethane materials have the advantages of adjustable curing speed, high compression resistance, high bond strength, and good toughness, but the material itself is high in cost and flammable. In addition, the material reacts with a large heat release, and there are many safety production accidents caused by polyurethane reinforcement materials.

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0047] Below, the structural principle of the present invention and the working principle are described in detail:

[0048] The organic reinforcing material for mining of the present invention is a cross-linked polymer formed by the addition polycondensation reaction of mixed polyether polyol and crude MDI, which is a macromolecule of a general-purpose unsaturated polyester resin and a hydroxyethyl acrylate-terminated polyurethane prepolymer. The cross-linked polymers generated by bulk free radical polymerization interact to form structural polymers with fully interpenetrating networks. Wherein, the heat generated during the addition polycondensation reaction of the mixed polyether polyol and the crude MDI promotes the double bond in the unsaturated polyester and the double bond in the hydroxyethyl acrylate-terminated polyurethane prepolymer macromonomer. The bond undergoes a free-radical polymerization reaction.

[0049] Wherein, the structural polymer includes A component a...

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PUM

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Abstract

Disclosed are an organic reinforcement mine material and a preparation method thereof. A cross-linked polymer is generated from addition polycondensation reaction of mixed polyether polyol and rough MDI (diphenylmethane diisocyanate), a cross-linked polymer is generated from polymerization reaction of general unsaturated polyester resin and macromonomer free radical of hydroxyethyl acrylate-terminated polyurethane prepolymer, and the two cross-linked polymers are enabled to interact to generate a full interpenetrating network structure polymer. The preparation method includes: according to setmass portion, adding raw materials for a component A into a mixing container sequentially, and evenly mixing by stirring at normal temperature to obtain the component A; adding raw materials for a component B into another mixing container sequentially, and mixing uniformly by stirring at normal temperature to obtain the component B; evenly mixing the component A and the component B at the mass ratio of 1:1 by stirring quickly at normal temperature, and allowing the mixed materials to react and cure quickly so generate the organic reinforcement mine material.

Description

technical field [0001] The invention relates to the technical field of mining reinforcing materials, in particular to an organic mining reinforcing material and a preparation method thereof. Background technique [0002] With the increase of mineral mining depth and the emergence of complex terrain, dangerous accidents such as roof caving and ganging caused by fault fracture zones and unstable strata not only affect the production efficiency of enterprises, but also seriously threaten the safety of miners. Therefore, in the production process, grouting reinforcement is generally required. At present, the most widely used organic polymer grouting reinforcement materials include polyurethane, urea-formaldehyde, phenolic and so on. Although urea-formaldehyde and phenolic reinforced materials have the advantages of good permeability, adjustable gelation speed and low cost, their disadvantages such as low strength and brittleness make them not widely recognized. Polyurethane ma...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L75/08C08L75/14C08L67/06C08K5/521C08K5/18C08K5/098C08K5/134
CPCC08L75/08C08L2201/02C08L2205/03C08L2205/04C08L75/14C08L67/06C08K5/521C08K5/18C08K5/098C08K5/1345
Inventor 王建中王涛
Owner 山西凝固力新型材料股份有限公司