A temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water

A high-salinity, temperature-resistant and salt-resistant technology, which is used in mining fluids, drilling compositions, chemical instruments and methods, etc. Application and other issues, to achieve the effect of improving oil washing efficiency, improving temperature and salt resistance, and reducing gas-liquid mass transfer speed

Active Publication Date: 2020-10-16
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Tertiary oil recovery mainly changes the water-oil mobility ratio by adding chemical substances, thereby enhancing oil recovery. At present, alkali flooding, polymer flooding, surfactant flooding, and binary or three-element compound flooding are commonly used. The tertiary oil recovery method is currently difficult to adapt to high temperature and high salinity formations, and it is difficult to overcome the limited degree of enhanced oil recovery and other problems
For Xinjiang Tahe Oilfield, where fresh water resources are scarce and reservoir conditions are relatively harsh (temperature is 130°C, total salinity is 220,000 mg / L), the use of simple surfactants is firstly difficult to configure, and secondly, the foam system is under high-temperature and high-salt conditions Defoaming is easy to occur, and most of the current oil displacement foam systems use organic foam stabilizers, which have poor heat and salt resistance and cannot be applied to high temperature and high salt reservoirs

Method used

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  • A temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water
  • A temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water
  • A temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water

Examples

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preparation example Construction

[0042] A method for preparing a temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water, the steps are as follows:

[0043] (1) At 25°C, add citrate to the water first, stir for 3-5 minutes to fully dissolve the citrate, and then add nano-SiO 2 After stirring for 3-5 minutes, sonicate for 60 minutes to make nano-SiO 2 Can be uniformly dispersed in water to obtain nano-SiO 2 dispersed aqueous solution;

[0044] (2) In nano-SiO 2 Disperse the aqueous solution and then add the surfactant THSB, stir for 3-5 minutes to fully dissolve, and obtain the first mixed solution;

[0045] (3) Partially hydrolyzed HPAM was added to the first mixed solution, and the solution was stirred for 6 hours to obtain a temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water.

[0046] An oil displacement method of a temperature-resistant and salt-resistant foam control and flo...

Embodiment 1

[0057] This example evaluates the flocculation, foaming and foam stabilization performance of the temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water.

[0058] At 25°C, prepare nano-SiO 2 The mass fraction is 1%, the mass fraction of THSB is 0.05%, the mass fraction of partially hydrolyzed HPAM is 0.1%, the average molecular weight is 4 million, the degree of hydrolysis is 6%, the mass fraction of sodium citrate is 0.1%, and the balance is a composite system solution of water , the water is simulated mineralized water prepared according to reservoir conditions, the total salinity is 220000mg / L, where Ca2+ with Mg 2+ The ion concentration is 2000mg / L.

[0059] Such as figure 1 As shown, under the unstirred condition, the control and flooding system has less flocculation at 25°C and 220,000 mg / L. After aging under high temperature conditions, as figure 2 As shown, a large amount of flocculation will be formed ...

Embodiment 2

[0064] A temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water, including the following components by mass fraction: 1.5% nano-SiO 2 , 0.1% THSB, 0.15% partially hydrolyzed polyacrylamide (HPAM), the average molecular weight is 6 million, the degree of hydrolysis is 8%, 0.1% potassium citrate, the balance is water, and the sum of the mass fractions of each component is 100% , the water is simulated mineralized water prepared according to reservoir conditions, the total salinity is 220000mg / L, where Ca 2+ with Mg 2+ The ion concentration is 2000mg / L.

[0065] A method for preparing a temperature-resistant and salt-resistant foam control and flooding system prepared from high-salinity formation water, the steps are as follows:

[0066] (1) At 25°C, add 0.15g of potassium citrate to 99.25g of simulated mineralized water, stir to fully dissolve the potassium citrate, and then add 1.5g of nano-SiO 2 Stir for 3-5 min...

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Abstract

The invention discloses a temperature-resisting salt-tolerant foam adjusting displacing system prepared from high-salinity formation water. The temperature-resisting salt-tolerant foam adjusting displacing system comprises the following components by weight percent: 0.5%-2% of nano-SiO2, 0.01-2% of THSB, 0.01-0.5% of HPAM, 0.01-0.3% of citrate and the balance of water. The invention discloses a preparation method of the temperature-resisting salt-tolerant foam adjusting displacing system. The preparation method comprises the following steps: firstly adding citrate and nano-SiO2 into water at 25 DEG C; stirring and then ultrasonically treating; adding THSB and stirring; adding partial hydrolysis HPAM and stirring, thereby acquiring the end product. The invention also discloses an oil displacement method adopting the adjusting displacing system. The oil displacement method comprises the following steps: (1) injecting a THSB aqueous solution on a prepositioned pretreated section into stratum; (2) injecting an adjusting displacing system and a pure nitrogen system of a main section into stratum; (3) injecting a nano-SiO2 aqueous solution on a post-positioned protection section into stratum; (4) closing well for 5-10 days, opening the well and recovering production. The compound adjusting displacing system provided by the invention can be applied to high-temperature high-salinity oil deposit and has high ageing stability. Multiple alternate oil displacing sections are arranged, so that the oil displacement effect of the system is extremely promoted.

Description

technical field [0001] The invention relates to the technical field of petroleum exploitation, in particular to a temperature-resistant and salt-resistant foam control and flooding system prepared from formation water with high salinity. Background technique [0002] After primary oil recovery and secondary oil recovery in major domestic oil fields, the water content of crude oil has risen steadily, and most oil fields have entered the stage of tertiary oil recovery. Tertiary oil recovery mainly changes the water-oil mobility ratio by adding chemical substances, thereby enhancing oil recovery. At present, alkali flooding, polymer flooding, surfactant flooding, and binary or three-element compound flooding are commonly used. At present, the tertiary oil recovery method is difficult to adapt to high-temperature and high-salt formations, and it is difficult to overcome the limited degree of enhanced oil recovery and other problems. [0003] Nanomaterials are emerging materials...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C09K8/58E21B43/22
CPCC09K8/58C09K2208/10E21B43/16
Inventor戴彩丽吴一宁赵明伟
OwnerCHINA UNIV OF PETROLEUM (EAST CHINA)