A method for stabilizing the quality of hydrocracking products

A technology for hydrocracking and product quality, which is applied in hydrotreating process, hydrocarbon oil treatment, petroleum industry, etc. It can solve the problems of high bromine index and exceeding standard of heavy naphtha, reduce acidity and hydrogenation performance, prolong The effect of operating cycle and reducing the severity of the reaction

Active Publication Date: 2020-12-08
CHINA PETROLEUM & CHEM CORP +1
View PDF12 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Aiming at the problems in the prior art that the olefins that commonly exist in the late stage of the hydrocracking reaction process using post-treatment catalysts exceed the standard, that is, the bromine index of heavy naphtha is too high, the mercaptans are too high, and the sulfur of aviation fuel products exceeds the standard. The use of grading and temperature control provide a method to improve the quality stability of hydrocracking products

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A method for stabilizing the quality of hydrocracking products
  • A method for stabilizing the quality of hydrocracking products
  • A method for stabilizing the quality of hydrocracking products

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] use figure 1 In the process flow shown, A and B are used for the treatment catalyst, C1 is used for the cracking catalyst, the conversion rate of the reaction mass is controlled to 85%, the operation time is 20 months, and the bromine index of heavy naphtha is sampled and analyzed.

Embodiment 2

[0042] use figure 1 In the process flow shown, A and B are used for the treatment catalyst, C2 is used for the cracking catalyst, the conversion rate of the reaction mass is controlled to 85%, the operation time is 24 months, and the bromine index of heavy naphtha is sampled and analyzed.

Embodiment 3

[0046] use figure 1 In the process flow shown, A and B are used for the treatment catalyst, C3 is used for the cracking catalyst, the conversion rate of the reaction mass is controlled to 86%, and the operation time is 26 months. Sampling and analysis of bromine index of heavy naphtha is carried out.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
specific surface areaaaaaaaaaaa
specific surface areaaaaaaaaaaa
Login to view more

Abstract

The invention discloses a method for stabilizing the quality of a hydrocracking product. The method comprises the following steps that hydrocracking raw materials and hydrogen gas are mixed to enter ahydrocracking pretreatment reactor for refining reaction; reaction effluents enter a hydrocracking reactor for hydrocracking reaction; four hydrocracking catalyst bed layers are arranged in the hydrocracking reactor; hydrogenation posttreatment catalyst bed layers are arranged at the bottom of the hydrocracking reactor; when the conversion rate of fractions higher than 350 DEG C in hydrocrackingraw materials is 80 to 89 percent, the hydrogenation posttreatment catalyst bed layers are arranged between the hydrocracking catalyst bed layers; the volume ratio of hydrogenation posttreatment catalysts between the bed layers along the material flow direction to the hydrogenation posttreatment catalysts filled at the reactor bottom is (5 to 15):(10 to 30):(20 to 40):(30 to 50); the volume ratioof the hydrogenation posttreatment catalysts (total weight) filled in the hydrocracking reactor to hydrocracking catalysts (total weight) filled in the hydrocracking reactor is 1:(6 to 8); after hydrocracking products are separated, various products are obtained. By the method, the quality stability of the hydrocracking products can be obviously improved.

Description

technical field [0001] The invention relates to a method for stabilizing the quality of hydrocracking products, in particular to a method for stabilizing the quality of heavy naphtha products in late hydrocracking products during long-term operation. Background technique [0002] The hydrocracking process is under the action of hydrogen, high temperature, high pressure and catalysts to hydrodesulfurize, hydrodenitrogenate, polycyclic aromatic hydrocarbons, hydrosaturation and ring-opening cracking of heavy distillate oils (VGO, CGO, DAO). The process of converting into light oil and middle distillate oil has the characteristics of flexible operation, good product quality and environmental friendliness. As one of the main processes for the deep processing of heavy distillate oil, it is not only the production of light oil products in the refining industry It has become an important means of petrochemical enterprises, and has become the key technology of petrochemical enterpri...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C10G65/12
Inventor 王仲义崔哲彭冲孙士可吴子明曹正凯
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products