Catalytic diesel oil hydro-conversion method

A catalytic diesel and hydrogenation conversion technology, which is applied in the fields of hydrotreating process, petroleum industry, and hydrocarbon oil treatment, can solve the problem of poor selectivity of single-ring aromatic hydrocarbons, and achieve high surface energy, low diffusion resistance, and accelerated adsorption speed Effect

Active Publication Date: 2019-05-21
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

On the basis of systematically grasping the influence of operating conditions such as reaction pressure and reaction temperature on aromatics saturation, two different hydrofining reaction zones are set up to solve the problem of single-ring aromatics selection in the conventional hydrofining process of high-aromatic diesel feedstock sex problem

Method used

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  • Catalytic diesel oil hydro-conversion method

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Embodiment 1~3

[0037] Embodiment 1~3 all adopts flow process of the present invention, figure 1 The combined process flow shown. After being heated by the heating furnace, the high-aromatic catalytic diesel oil is mixed with circulating hydrogen and enters the I hydrorefining reaction zone for hydrodesulfurization, polycyclic aromatic hydrocarbons selective hydrogenation saturation and other reactions; the obtained oil is mixed with circulating hydrogen and enters II hydrorefining reaction zone The reaction zone carries out further hydrodesulfurization reaction and aromatics selective reaction; the obtained oil is mixed with circulating hydrogen and enters the hydrocracking reaction area for hydrocarbon hydroconversion reaction; the obtained oil is separated and fractionated to obtain gas, pumice Naphtha, heavy naphtha, diesel fractions. Part of the diesel is recycled back to the II hydrorefining reaction zone, and part of the diesel is sent out of the unit. The gas is recycled through the...

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Abstract

The invention discloses a catalytic diesel oil hydro-conversion method. The catalytic diesel oil hydro-conversion method comprises the following steps: (1) mixing high aromatic hydrocarbon catalytic diesel oil with circulating hydrogen and feeding the mixture into a hydrofining reaction zone I for reaction; (2) mixing generated oil obtained in the step (1) with circulating hydrogen, and feeding the mixture into a hydrofining reaction zone II for further reaction, wherein the reaction temperature is 30-120 DEG C higher than that of the hydrofining reaction zone I, and the liquid hourly space velocity is 0.2-1.5 h<-1> lower than that of the hydrofining reaction zone I; (3) mixing the generated oil obtained in the step (2) with circulating hydrogen, feeding the mixture into a hydrocracking reaction zone for hydrocarbon hydro-conversion reaction; and (4) enabling the generated oil obtained in the step (3) to pass through a separation and fractionation system to obtain gas, light naphtha, heavy naphtha and diesel oil fractions, returning part of diesel oil to the hydrofining reaction zone II, and discharging the other part of the diesel oil from the device. By the catalytic diesel oil hydro-conversion method, the yield of aromatic hydrocarbons can be increased effectively.

Description

technical field [0001] The invention relates to the field of petroleum refining. Specifically, it relates to a method for processing catalytic diesel to produce high-quality gasoline and high-quality diesel. Background technique [0002] Catalytic cracking is currently the most important secondary processing process in the petroleum refining industry, and it is also the core process of lightening heavy oil. As the world's oil becomes increasingly heavy, the processing capacity of the FCC unit is also continuously improved. Using various heavy oils as raw materials, high-octane gasoline, the main product, is obtained through catalytic cracking reactions, and a large amount of sulfur, nitrogen, and aromatics are produced at the same time. Catalytic diesel oil with high content, low cetane number or cetane index, and extremely poor stability. Moreover, the requirements of environmental protection regulations are becoming more and more stringent, and the indicators of diesel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G67/02
Inventor 彭冲杜艳泽曾榕辉吴子明王仲义崔哲隋宝宽
Owner CHINA PETROLEUM & CHEM CORP
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