Colorant compound and coloring composition containing same
A technology of compounds and colorants, applied in the directions of organic chemistry, chemical instruments and methods, photoengraving process of pattern surface, etc., to achieve the effects of excellent color reproducibility, excellent light resistance, and excellent heat resistance
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Synthetic example 1
[0128] Synthesis Example 1: Synthesis of Compound 1
[0129]
[0130]1.084 g (4.330 mmol) of compound B-1 was added and stirred to 50 g of dichloromethane. Set the ice bath (icebath) to make it 0°C, then add 0.830 g (4.330 mmol) of N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride (N-( 3-Dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride) (EDC-HCl), stirred for 15 minutes. Add a small amount of dimethylformamide, 0.141g (1.155mmol) of 4-dimethylaminopyridine, add 0.737g (1.443mmol) of compound A-1, react at 0°C for 2 hours, and react overnight at room temperature ). Further add 100 ml of dichloromethane and 50 ml of dichloromethane for extraction, and pass the organic layer through Na 2 SO 4 The water was removed and the solvent was removed under reduced pressure. Then, the precipitate was separated by column chromatography (eluent-dichloromethane:methanol). As a result, the title compound 1 (0.422 g, 0.433 mmol) was obtained in a yield of 30%.
[013...
Synthetic example 2
[0132] Synthesis Example 2: Synthesis of Compound 2
[0133]
[0134] 1.084 g (4.330 mmol) of compound B-1 was added and stirred to 100 g of dichloromethane. Set the ice bath (icebath) to make it 0°C, then add 0.830g (4.330mmol) of N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride (EDC-HCl ), and stirred for 15 minutes. Add a small amount of dimethylformamide, 0.141g (1.155mmol) of 4-dimethylaminopyridine, add 2.211g (4.330mmol) of compound A-1, react at 0°C for 2 hours, and react overnight at room temperature ). Further add 100ml of dichloromethane, 50g of dichloromethane and extract, and make the organic layer pass through Na 2 SO 4 The water was removed and the solvent was removed under reduced pressure. Then, the precipitate was separated by column chromatography (eluent-dichloromethane:methanol). As a result, the title compound 2 (0.804 g, 1.083 mmol) was obtained in a yield of 25%.
[0135] Ionization mode =: APCI+: m / z = 743.3[M+H]+, exact mass: 742...
Synthetic example 3
[0136] Synthesis Example 3: Synthesis of Compound 3
[0137]
[0138] In synthesis example 1, it synthesize|combined by the method similar to synthesis example 1 except having used the compound B-2 of 1.205g (4.33 mmol) instead of compound B-1. As a result, the title compound 3 (0.670 g, 0.650 mmol) was obtained in a yield of 45%.
[0139] Ionization mode =: APCI+: m / z = 1031.5[M+H]+, exact mass: 1030.5
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More