A kind of phenol wastewater treatment method
A waste water treatment, waste water technology, applied in the direction of water/sewage treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc., can solve the problems of low industrialization, immaturity, and few research results of solar energy utilization methods , achieve the effect of saving energy and breaking limitations
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Embodiment 1
[0099] The phenol wastewater treatment method of the present embodiment comprises the steps:
[0100] Heat the sealed reactor to 150°C in advance through the thermal energy provided by the solar concentrating heat collector. The reactor is provided with a liquid inlet for adding phenol wastewater, and the phenol wastewater is discharged through the temperature-resistant liquid inlet pipe arranged on the liquid inlet. Added into the reactor, the concentration of phenol wastewater is 500mg / L (referring to the phenol content is 500mg / L), and the phenol wastewater reaches the boiling point and vaporizes after entering the reactor, turning into phenol water vapor.
[0101] Through the electric energy provided by the photovoltaic cell, a direct current is passed into the phenol water vapor in the reactor to electrolytically oxidize the vapor state phenol. The electrolytic oxidation adopts a bipolar system, and both the cathode and the anode are nickel electrodes. The electrolysis t...
Embodiment 2 to Embodiment 9
[0103] The processing methods of Embodiment 2 to Embodiment 9 are basically the same as Embodiment 1, except that the electrolysis voltages are 2V, 3V, 4V, 5V, 6V, 7V, 8V and 9V respectively.
[0104] It was found that almost no current was generated in the reactors of Examples 1 to 4, and phenol could not be effectively electrolyzed under the condition of 150°C / <5V.
[0105] figure 1It is the ultraviolet spectrogram after the degradation of the phenol waste water of embodiment 5 to embodiment 9. from
[0106] figure 1 It can be seen that when the electrolysis voltage is 5V, compared with the characteristic absorption peak of phenol before degradation, the decrease is more significant, and there is an absorption peak between 260-265nm, which may be due to the incomplete oxidation of phenol during the degradation process. caused by the product. When the electrolysis voltage increased to 6V, 7V, 8V, the characteristic absorption peak of phenol decreased more obviously. Fina...
Embodiment 10
[0109] Embodiment 10 is substantially the same as Embodiment 9, the difference is:
[0110] Heat the sealed reactor to 170°C in advance with the heat energy provided by the solar concentrating heat collection device;
[0111] The electrolysis temperature is 170°C, and the thermal energy provided by the solar concentrating heat collection device continues to provide the required temperature environment for electrolysis.
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