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A kind of red mud soil matrix and preparation method thereof

A technology for red mud and soil is applied in the field of red mud soil matrix and its preparation, and can solve the problems of fugitive dust polluting the air, poor air permeability, complicated process and the like

Active Publication Date: 2021-05-14
ZHENGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Red mud is solid waste generated during the alumina production process. The total stock of red mud in my country exceeds 600 million tons, and about 100 million tons of red mud are produced every year. A large amount of red mud stockpiles not only occupies land resources, but also causes serious ecological problems near the stockyard. Hazard, the strong alkalinity of red mud makes the stockyard barren, and it is easy to generate dust to pollute the air. Harmful elements in red mud are easy to migrate to groundwater and soil to pollute groundwater and soil, and the maintenance of the stockyard requires a certain amount of money.
At present, a lot of research has been carried out on the comprehensive utilization of red mud, mainly including the extraction of valuable components, the preparation of functional materials, the preparation of building materials, etc.; red mud contains a certain amount of metal resources, and the extraction of valuable metals has complex processes, high costs, and secondary Secondary pollution and other issues; the preparation of high value-added functional materials is basically in the research stage, and the consumption of red mud is very limited for this technical idea; building materials such as sintered bricks, non-steamed bricks, and cement can be consumed and utilized in large quantities from red mud Red mud, but the strong alkalinity of red mud seriously affects the product quality, and the dealkalization technology has high cost and complicated process
[0003] Regulating red mud into a soil matrix for plant growth to achieve ecological restoration, to achieve reduction and harmlessness of red mud, has a very good application prospect; red mud has strong alkalinity and rich mineral elements, and some studies have shown that red mud The use of mud to regulate acidic soil can better promote plant growth, but red mud itself has very poor soil properties, strong alkalinity, low water holding rate, poor air permeability, easy compaction, and low organic nutrient content, so it is difficult to directly use soil

Method used

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  • A kind of red mud soil matrix and preparation method thereof
  • A kind of red mud soil matrix and preparation method thereof
  • A kind of red mud soil matrix and preparation method thereof

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preparation example Construction

[0045] The application provides a preparation method of red mud soil matrix, such as figure 1 shown, including the following steps:

[0046] Step S1, using a crusher to crush the biomass raw material into biomass powder;

[0047] Step S2, transporting biomass powder, water and catalyst into a stirring tank for stirring to obtain a mixture;

[0048] Step S3, adding the mixture to the autoclave at a speed of V 1 The autoclave is heated up to T 1 After that, keep it warm for 5-20 hours; then cool to room temperature to obtain the hydrothermal carbonization product;

[0049] Step S4, performing solid-liquid separation on part of the hydrothermal carbonization products to obtain hydrothermal charcoal and hydrothermal charcoal liquid; the remaining hydrothermal carbonization products are set aside;

[0050] Step S5, carbonizing the hydrothermal charcoal to obtain modified hydrothermal charcoal;

[0051] Step S6, mix the modified hydrothermal charcoal, the remaining hydrothermal...

Embodiment 1

[0098] The preparation method of the red mud soil matrix of the present embodiment may further comprise the steps:

[0099] Step S1, adding the biomass raw material (in this embodiment, straw) into the crusher 1, and the crusher 1 crushes the straw into a powder with a particle size of 1 mm;

[0100] Step S2, use the material lifting mechanism 4 to transport the powder into the mixing tank 2 from the first feeding port, and then add water and catalyst (the catalyst is red mud in this embodiment) into the mixing tank 2 through the second feeding port , stirring to obtain a mixture, the stirring speed is 500rpm, the stirring time is 10min, and the mass ratio of powder, water and catalyst is: 0.05:1:0.0025;

[0101] Step S3, adding the mixture to the autoclave 3, heating the autoclave 3 at 200°C / h, and keeping the temperature at 200°C for 20 hours; then cooling to room temperature to obtain a hydrothermal carbonization product; wherein, the mixture Volume is 1 / 3 of the volume of...

Embodiment 2

[0107] The preparation method of the red mud soil matrix of the present embodiment may further comprise the steps:

[0108] Step S1, adding the biomass raw material (fallen leaves in this embodiment) into the crusher 1, and the crusher 1 crushes the fallen leaves into a powder with a particle size of 3mm;

[0109] Step S2, use the material lifting mechanism 4 to transport the powder into the stirring tank 2 from the first feeding port, and then add water and catalyst (the catalyst is potassium carbonate in this embodiment) into the stirring tank 2 through the second feeding port , stirring to obtain a mixture, the stirring speed is 200rpm, the stirring time is 30min, and the mass ratio of powder, water and catalyst is: 0.2:1:0.01;

[0110] Step S3, adding the mixture to the autoclave 3, heating the autoclave 3 at 150°C / h, and keeping the temperature at 380°C for 10 hours; then cooling to room temperature to obtain a hydrothermal carbonization product; wherein, the mixture Vol...

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Abstract

The application discloses a red mud soil substrate and a preparation method thereof, which belong to the technical field of red mud ecological restoration, and solve the problems of large amount of alkaline regulating chemical substances in the existing red mud and complex and high cost of other components during red mud soil treatment. The problem of small red mud consumption. The preparation method includes: crushing biomass raw materials; transporting biomass powder, water and catalyst into a stirring tank to stir to obtain a mixture; adding the mixture to a high-pressure reactor, raising the temperature, keeping it warm, and then cooling to room temperature to obtain a hydrothermal carbonization product; Part of the hydrothermal carbonization product is separated into solid and liquid to obtain hydrothermal charcoal and hydrothermal charcoal liquid; the remaining hydrothermal carbonization product is used for standby; hydrothermal charcoal is carbonized to obtain modified hydrothermal charcoal; modified hydrothermal charcoal, hydrothermal charcoal The carbonization product and the red mud are mixed and put into a stirring tank, stirred and placed to obtain a red mud soil matrix. The red mud soil matrix includes a stirred mixture of modified hydrothermal charcoal, hydrothermal carbonization products, and red mud. This application realizes the ecological restoration of red mud.

Description

technical field [0001] The present application relates to red mud ecological restoration technology, in particular to a red mud soil matrix and a preparation method thereof. Background technique [0002] Red mud is a solid waste produced during the alumina production process. The total stock of red mud in my country exceeds 600 million tons, and about 100 million tons of red mud are produced every year. A large amount of red mud stockpiles not only occupies land resources, but also causes serious ecological problems near the stockyard. Harm, the strong alkalinity of red mud makes the stockyard barren, and it is easy to generate dust to pollute the air. Harmful elements in red mud are easy to migrate to groundwater and soil to pollute groundwater and soil, and the maintenance of the stockyard requires a certain amount of money. At present, a lot of research has been carried out on the comprehensive utilization of red mud, mainly including the extraction of valuable components,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A01G24/22A01G24/23A01G24/17A01G24/60B01F15/02B01F13/10
CPCA01G24/22A01G24/23A01G24/17A01G24/60B01F33/80B01F33/831B01F33/8362B01F35/717
Inventor 曹亦俊王重庆
Owner ZHENGZHOU UNIV
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