Secondary amide cyclamine quaternary ammonium salt amphoteric asphalt emulsifier and preparation method thereof
A technology of asphalt emulsifier and secondary amide cyclic amine, which is applied in the field of fine chemical industry, can solve the problems of high requirements for production experimental equipment, high cost of emulsifier raw materials, complicated preparation steps, etc., and achieves excellent performance indicators and good aggregate adhesion. and storage stability, the effect of improving stability
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[0036] For above asphalt emulsifier, the present invention also provides its preparation method, comprises the following steps:
[0037] (1) Aminoethylpiperazine, alcoholic solvent and acrylic acid are mixed and reacted to obtain reaction intermediate I, and the structural formula of said reaction intermediate I is:
[0038]
[0039] (2) Add epichlorohydrin gradually again in reaction intermediate I, mixed reaction, obtain reaction intermediate II, the structural formula of described reaction intermediate II is:
[0040]
[0041](3) Gradually add cocoyl propyl dimethyl tertiary amine to the reaction intermediate II, mix and react, then add water, mix and react, and obtain the secondary amide cyclic amine quaternary ammonium salt amphoteric asphalt emulsifier.
[0042] In some preferred technical schemes of the present invention, the mol ratio of cocoyl propyl dimethyl tertiary amine, alcoholic solvent, water, epichlorohydrin, aminoethylpiperazine, acrylic acid is 1mol: (...
Embodiment 1
[0063] (1) Preparation of secondary amide cyclic amine quaternary ammonium salt amphoteric asphalt emulsifier:
[0064] 1) Add 141.9g aminoethylpiperazine, 300g isopropanol in the reactor, heat and stir to mix. Then gradually added 79.3g of acrylic acid, and stirred at 75°C for 2h to obtain reaction intermediate I.
[0065] 2) Gradually add 97.07 g of epichlorohydrin to the reaction intermediate I. After the addition is complete, react at 75° C. for 2 hours to obtain the reaction intermediate II.
[0066] 3) Gradually add 284.5g cocoyl propyl dimethyl tertiary amine to the reaction intermediate II. After the addition is complete, react at 75°C for 0.5h, then add 300g of water. After adding water, react at 75°C for 3h. That is, the amphoteric asphalt emulsifier of secondary amide cyclic amine quaternary ammonium salt was obtained, which was reserved for the emulsified asphalt test.
[0067] The synthesized product was separated and purified by recrystallization and then detec...
Embodiment 2
[0076] (1) Preparation of secondary amide cyclic amine quaternary ammonium salt amphoteric asphalt emulsifier:
[0077] 1) Add 141.9g aminoethylpiperazine and 300g dehydrated ethanol in the reactor, heat and stir to mix. Then gradually added 79.3g of acrylic acid, and stirred at 65°C for 3h to obtain reaction intermediate I.
[0078] 2) Gradually add 97.07 g of epichlorohydrin to the reaction intermediate I. After the addition is complete, react at 75° C. for 2 hours to obtain the reaction intermediate II.
[0079] 3) Gradually add 284.5g cocoyl propyl dimethyl tertiary amine to the reaction intermediate II. After the addition is complete, react at 75°C for 0.5h, then add 300g of water. After adding water, react at 75°C for 3h. That is, the amphoteric asphalt emulsifier of secondary amide cyclic amine quaternary ammonium salt was obtained, which was reserved for the emulsified asphalt test.
[0080] (2) Preparation of emulsified asphalt:
[0081] Take 300g of AH-70# asphalt...
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