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A non-burning adsorbent for removing organic pollutants in water based on iron-containing solid waste

A technology for organic pollutants and adsorbents, which is applied in the field of non-burning type adsorbents for removing organic pollutants in water, can solve the problems of high cost and complex preparation process, and achieves low cost, simple process, economical and environmental benefits. Effect

Active Publication Date: 2020-10-27
HEBEI UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these existing adsorbents have good adsorption effects on perfluorinated compounds and polycyclic aromatic hydrocarbons, their cost is relatively high and the preparation process is complicated.
At present, there are relatively few reports on the preparation of non-burning adsorbents for purifying organic pollutants such as perfluorinated compounds and polycyclic aromatic hydrocarbons in water using cheap solid waste with fixed components as the main raw material.

Method used

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  • A non-burning adsorbent for removing organic pollutants in water based on iron-containing solid waste
  • A non-burning adsorbent for removing organic pollutants in water based on iron-containing solid waste
  • A non-burning adsorbent for removing organic pollutants in water based on iron-containing solid waste

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] (1) Adsorbent preparation

[0029] 1) Dry mixing: Grind the iron-containing solid waste, coal gangue and binder through a 200-mesh sieve and mix well, then let stand for 3 minutes. The binder is cement, and the content of each component in the raw material is 75% of iron-containing solid waste; 15% of coal gangue; and 10% of cement. The mass composition of described iron-containing solid waste is: SiO 2 : 55%, Fe 2 o 3 : 15%, TiO 2 : 10%, MgO: 10%, organic matter: 5%, others: 5%.

[0030] 2) Wet mixing: Add the mixed materials into the mixer, add water according to the liquid-solid ratio of 1:10, and stir at a speed of 120r / min for 10min until the materials are fully mixed.

[0031] 3) Extrusion molding: Put the uniformly stirred material into the mold, extrude and vibrate to form a ball with a diameter of 1 mm, and start curing after standing for 24 hours. After extrusion, the surface of the ball has a certain roughness.

[0032] 4) Natural maintenance: Cover the...

Embodiment 2

[0042] (1) Adsorbent preparation

[0043] 1) Dry mixing: Grind the iron-containing solid waste, coal gangue and binder through a 200-mesh sieve and mix well, then let stand for 3 minutes. The content of each component in the raw material is 75% of iron-containing solid waste; 15% of coal gangue; and 10% of cement. The mass composition of described iron-containing solid waste is: SiO 2 : 55%, Fe 2 o 3 : 15%, TiO 2 : 10%, MgO: 10%, organic matter: 5%, others: 5%.

[0044]2) Wet mixing: Add the mixed materials into the mixer, add water according to the liquid-solid ratio of 1:10, and stir at a speed of 120r / min for 10min until the materials are fully mixed.

[0045] 3) Extrusion molding: put the uniformly stirred material into the mold, extrude and vibrate to form a ball with a diameter of 1 mm, and start curing after standing for 24 hours.

[0046] 4) Natural maintenance: Cover the formed material ball with a straw mat, spray water evenly every 5 days to keep it moist, and...

Embodiment 3

[0056] (1) Adsorbent preparation

[0057] 1) Dry mixing: Grind the iron-containing solid waste, coal gangue and binder through a 200-mesh sieve and mix well, then let stand for 3 minutes. The content of each component in the raw material is 75% of iron-containing solid waste; 15% of coal gangue; and 10% of cement. The mass composition of described iron-containing solid waste is: SiO 2 : 55%, Fe 2 o 3 : 15%, TiO 2 : 10%, MgO: 10%, organic matter: 5%, others: 5%.

[0058] 2) Wet mixing: Add the mixed materials into the mixer, add water according to the liquid-solid ratio of 1:10, and stir at a speed of 120r / min for 10min until the materials are fully mixed.

[0059] 3) Extrusion molding: put the uniformly stirred material into the mold, extrude and vibrate to form a ball with a diameter of 1 mm, and start curing after standing for 24 hours.

[0060] 4) Natural maintenance: Cover the formed material ball with a straw mat, spray water evenly every 5 days to keep it moist, an...

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Abstract

The invention relates to an iron-containing solid waste-based burn-free adsorbent for removing organic pollutants in a water body. According to the adsorbent, iron-containing solid waste with specificcomponents, coal gangue and a binder are used as raw materials, and dry mixing, wet mixing, extrusion forming and natural curing are performed to prepare the baking-free adsorbent for removing organic pollutants in a water body. Wherein the raw materials comprise the following components in percentage by mass: 45-85% of iron-containing solid waste, 5-20% of coal gangue and 10-35% of binder; the iron-containing solid waste is prepared from, by mass, 55%-75% of SiO2, 10%-15% of Fe2O3, 5%-10% of TiO2, 5%-10% of MgO, 3%-5% of organic matter and 2%-5% of others. According to the adsorbent, the synergistic effect of iron-containing solid waste of specific components, coal gangue and active components in a binder is utilized. Meanwhile, a rough adsorbent surface is generated after natural maintenance, and efficient adsorption of organic pollutants in a water body is achieved under the combined action of physics and chemistry. The obtained adsorbent has the advantages of low cost, simple process and high adsorption efficiency.

Description

technical field [0001] The invention belongs to the technical field of water pollution control, and in particular relates to a burn-free adsorbent for removing organic pollutants in water bodies based on iron-containing solid waste. Background technique [0002] In recent years, with the acceleration of urban industrialization, a large amount of wastewater containing organic pollutants such as perfluorinated compounds and polycyclic aromatic hydrocarbons has been produced, and the resulting environmental pollution has become increasingly serious. Relevant studies have shown that organic pollutants such as perfluorinated compounds and polycyclic aromatic hydrocarbons are highly toxic and pose a serious threat to human health. Adsorption is considered to be an effective method to remove organic pollutants such as perfluorinated compounds, polycyclic aromatic hydrocarbons, and organic phosphorus from water bodies. The preparation of efficient and cheap adsorbents has become one...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/22B01J20/30C02F1/28C02F101/30C02F101/32C02F101/36
CPCB01J20/041B01J20/06B01J20/10B01J20/22C02F1/28C02F1/281C02F1/288C02F2101/30C02F2101/327C02F2101/36
Inventor 马小东陈子昂王淑荣
Owner HEBEI UNIV OF TECH