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Steel used for HIC-resistant pipe and preparation method of steel

A technology for pipes and steel billets, which is applied in the field of steel for anti-HIC pipes and its preparation. It can solve the problems of increased wall thickness of steel pipes, increased difficulty in manufacturing hydrogen-prone pipes, and low alloy strength, and achieves the effect of strong HIC resistance.

Active Publication Date: 2020-07-31
FOSHAN UNIVERSITY +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN102839326B provides a kind of alloy with low carbon content, through controlled rolling and air-cooling process, relatively fine ferrite structure is obtained, HIC resistance performance is improved, but the alloy strength is low, the resistance strength is 437MPa, it is difficult to meet the requirements of high strength, good toughness, Comprehensive properties such as hydrogen-induced cracking resistance
The increasingly large and high-pressure requirements of hydrogen pipelines make the wall thickness of steel pipelines continue to increase, which further increases the difficulty of manufacturing such hydrogen pipelines.

Method used

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  • Steel used for HIC-resistant pipe and preparation method of steel
  • Steel used for HIC-resistant pipe and preparation method of steel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] This example provides a steel for HIC resistant pipes, including the following components in mass percentage:

[0044] C: 0.05%, Cr: 1.20%, Cu: 0.80%, Ti: 1.0%, Sc: 0.15%, and the balance is Fe.

[0045] Among them, the S content is less than 0.01%, and the P content is less than 0.01%.

Embodiment 2

[0047] This example provides a method for preparing steel for HIC resistant pipes, including the following steps:

[0048] S1: Weigh the C, Cr, Cu, Ti, Sc, and Fe according to the ratio, and continuously cast after melting to obtain a steel billet;

[0049] S2: Heat the steel billet obtained in step S1 to obtain the HIC-resistant pipe steel.

[0050] among them. Heat treatment includes quenching and high temperature aging.

[0051] The quenching step is: heating the billet to 1100-1400°C at a heating rate greater than 300°C / s, holding it for 30 minutes, and then cooling it at the first cooling rate. The first cooling rate is greater than 100°C / s. The high-temperature aging step is: heating the billet to 700-750°C at a heating rate greater than 60°C / s, keeping it for 300 hours, and cooling it to a temperature lower than 50°C at a second cooling rate.

[0052] The second cooling rate is greater than 10°C / s.

Embodiment 3

[0054] This example uses the preparation method of Example 2 and refers to the formula of Example 1 to prepare a steel for HIC resistant pipes, which specifically includes the following components in mass percentages:

[0055] C: 0.02%, Cr: 1.40%, Cu: 1.0%, Ti: 0.6, Sc: 0.15%, the balance being Fe and impurity elements.

[0056] S content <0.01%. P content <0.01%.

[0057] In the preparation method, the heating temperature of the billet during quenching is 1250°C, and the heating temperature of the billet during high temperature aging is 725°C.

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Abstract

The invention provides steel used for an HIC-resistant pipe and a preparation method of the steel. The steel used for the HIC-resistant pipe comprises C, Cr, Cu, Ti, Sc and Fe and has high HIC resistance, and all HIC-sensitive indicators are zero. As for existing steel for the HIC-resistant pipe, although the HIC sensitivity of alloy can be reduced by designing low-carbon-content alloy, the strength of the alloy can be reduced. According to the steel used for the HIC-resistant pipe in the embodiment, a TiCuxSc phase is designed, so that the strength of the alloy steel is remarkably improved, and the hydrogen brittleness sensitivity of the alloy is reduced.

Description

Technical field [0001] The invention belongs to the field of steel preparation, and specifically relates to a steel for HIC resistant pipelines and a preparation method thereof. Background technique [0002] The construction of pipeline network is the strategic demand of various countries. Natural gas pipeline transportation has the characteristics of high efficiency, economy and safety, and is the main form of long-distance gas transportation. With the gradual changes in the international energy structure, the proportion of natural gas in energy will increase sharply in the next few decades. The development of natural gas pipelines tends to be large-diameter, high-pressure and thick-walled. The service conditions of pipelines are becoming more and more demanding. For example, the transportation pressure increases, the transportation medium is complicated, and many pipelines need to pass through densely populated areas or deserts, swamps and severe cold areas, which puts forwar...

Claims

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Application Information

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IPC IPC(8): C22C38/20C22C38/28C21D6/00C21D1/18
CPCC21D1/18C21D6/002C22C38/005C22C38/20C22C38/28
Inventor 聂宝华赵吉诗陈东初赵连玉王子缘
Owner FOSHAN UNIVERSITY