Film-forming softener containing natural conjugated unsaturated fatty acid and preparation method of softener

An unsaturated fatty acid, film-forming technology, used in dyeing methods, textiles and papermaking, improved hand-feeling fibers, etc., can solve the problem of natural color damage, easy to be decomposed by ultraviolet light, vegetable dyes dyed textiles weather resistance, light fast color fastness It can not meet the problems of industrial application, etc., and achieve the effect of solving weather resistance and soft and plump fabric feel.

Inactive Publication Date: 2021-06-18
苏州麻朵纺织科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Although plant dye dyeing technology has made some progress in recent years, a large part of the color of plant dye textiles has not been applied in large quantities, mainly because the natural colors of plant dye dyed textiles are easily affected by nitrogen oxides, ozone, etc. in the air. Oxidative damage is also easily decomposed by ultraviolet light. Commonly used petrochemical softeners will also aggravate this process, so that the weather resistance and light fastness of vegetable dyed textiles cannot meet the standards for industrial applications.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 1. Preparation of film-forming softener of natural conjugated unsaturated fatty acids

[0021] 1.1 Extract hibiscus leaf aqueous solution by high-temperature subcritical method:

[0022] Take fresh hibiscus leaves, use water as the solvent, the ratio of hibiscus leaves to water is 1:3 by weight, add 2g / l (calculated based on the volume of the mixture of hibiscus leaves and water) natural additive PO, extract at 125°C for 50 minutes, Extract once, and filter the extract with a 200-mesh filter.

[0023] 1.2 Preparation of composite acid degraded chitosan aqueous solution:

[0024] In the ultrasonic equipment, add 93% of pure water, 2% of wolfberry acid, 1% of tartaric acid, 2% of anisic acid or its sodium salt in sequence according to the weight percentage, turn on the agitator, and then add 2% of the weight percentage under the condition of stirring Chitosan with a molecular weight greater than 600,000 and a deacetylation degree greater than 90%. After the feeding is ...

Embodiment 2

[0031] 1. Preparation of film-forming softener of natural conjugated unsaturated fatty acids

[0032] 1.1 Extract hibiscus leaf aqueous solution by high-temperature subcritical method:

[0033] Take fresh hibiscus leaves, use water as the solvent, the ratio of hibiscus leaves to water is 1:3 by weight, add 3g / l (calculated based on the volume of the mixture of hibiscus leaves and water) natural additive PO, extract at 125°C for 50 minutes, Extract once, and filter the extract with a 200-mesh filter.

[0034] 1.2 Preparation of composite acid degraded chitosan aqueous solution:

[0035]In the ultrasonic equipment, add 92% of pure water, 2% of wolfberry acid, 1% of tartaric acid, 1% of anisic acid or its sodium salt in order by weight percentage, turn on the agitator, and then add 4% of Chitosan with a molecular weight greater than 600,000 and a deacetylation degree greater than 90%. After the feeding is completed, turn on the 28KHZ ultrasonic wave with a sound intensity of 1...

Embodiment 3

[0042] 1. Preparation of film-forming softener of natural conjugated unsaturated fatty acids

[0043] 1.1 Extract hibiscus leaf aqueous solution by high-temperature subcritical method:

[0044] Take fresh hibiscus leaves, use water as the solvent, the ratio of hibiscus leaves to water is 1:3 by weight, add 4g / l (calculated based on the volume of the mixture of hibiscus leaves and water) natural additive PO, extract at 125°C for 50 minutes, Extract once, and filter the extract with a 200-mesh filter.

[0045] 1.2 Preparation of composite acid degraded chitosan aqueous solution:

[0046] In the ultrasonic equipment, add 93.5% of pure water, 2% of wolfberry acid, 1% of tartaric acid, 0.5% of anisic acid or its sodium salt in order by weight percentage, turn on the agitator, and then add 3% by weight of Chitosan with a molecular weight greater than 600,000 and a deacetylation degree greater than 90%. After the feeding is completed, turn on the 28KHZ ultrasonic wave with a sound...

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PUM

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Abstract

The invention relates to the field of research, development and application of natural dyeing and finishing auxiliaries, in particular to a film-forming softener containing natural conjugated unsaturated fatty acid. The film-forming softener is composed of the following substances in percentage by weight of 0.5%-12% of conjugated octadecatrienoic acid such as trichosanic acid, punicic acid, calendic acid, jacoumaric acid and conjugated linolenic acid or octadecadienoic acid such as conjugated linoleic acid or esters thereof extracted from trichosanthes kirilowii seeds, 12-1% of fatty acid ester quaternary ammonium salt, 1-10% of a hibiscus leaf water extract solution, 0.01-0.5% of litsea cubeba oil, 0.2-1% of moringa oleifera oil, 0.5-8% of a chitosan aqueous solution, 0.01-0.05% of konjac glucomannan, and 85.78-67.45% of purified water. Compared with the prior art, the film-forming softener has the beneficial effects that a plant dyed fabric can be soft and plump in hand feeling, the weather resistance is improved, and the color fastness to light is higher than the grade of 0.5-1. The film-forming softener is suitable for natural textiles such as cotton, hemp, silk, wool and the like, and regenerated cellulose fiber textiles such as tencel, modal, viscose and the like, and is particularly suitable for softening processing of plant dyed textiles containing the raw materials.

Description

technical field [0001] The invention relates to the field of research and development and application of natural dyeing and finishing auxiliaries, in particular to a film-forming softener made of natural conjugated unsaturated fatty acids, such as trichosanthenic acid extracted from trichosanthes seeds or punicic acid extracted from pomegranate seeds. Background technique [0002] Although plant dye dyeing technology has made some progress in recent years, a large part of the color of plant dye textiles has not been applied in large quantities, mainly because the natural colors of plant dye dyed textiles are easily affected by nitrogen oxides, ozone, etc. in the air. Oxidative damage is also easily decomposed by ultraviolet light. Commonly used petrochemical softeners will also aggravate this process, so that the weather resistance and light fastness of textiles dyed with vegetable dyes cannot meet the standards for industrial applications. [0003] Conjugated unsaturated fa...

Claims

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Application Information

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IPC IPC(8): D06M13/00D06M13/203D06M13/224D06M13/463D06M15/03D06P1/34D06P5/04D06P5/08D06M101/06D06M101/10D06M101/12
CPCD06M13/00D06M13/203D06M13/2246D06M15/03D06M13/463D06P1/34D06P5/04D06P5/08D06M2200/50D06M2101/06D06M2101/12D06M2101/10D06M2200/25
Inventor 祝一鸣
Owner 苏州麻朵纺织科技有限公司
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