Multi-probe gas Raman spectrum system and mixed gas quantitative analysis method
A Raman spectroscopy, mixed gas technology, applied in Raman scattering, material excitation analysis, etc., can solve the problems of losing the timeliness of concentration information, unable to respond to gas sample concentration in real time, increasing cost, etc., achieving excellent portability and reducing deviation and error, the effect of reducing cost
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Embodiment 1
[0049] Embodiment 1, this embodiment proposes a kind of multi-probe gas Raman spectroscopy system, such as figure 1 As shown, it includes a laser 6, a Raman spectrometer 7, a CCD 8, and a plurality of gas Raman spectroscopy probes. The excitation light holes of the plurality of gas Raman spectroscopy probes are connected to the laser 6 through an excitation optical fiber 4, and the gas Raman spectroscopy probes The signal collection optical path is connected with the Raman spectrometer 7 through the signal collection fiber bundle 5, and then transmitted to the CCD8 for imaging;
[0050]Wherein, the excitation optical fiber 4 is a multi-fiber, and the number of excitation optical fibers 4 is consistent with the number of gas Raman spectroscopy probes; one end of the signal collection optical fiber bundle 5 is divided into multiple branches and connected to the gas Raman spectroscopy probes, The other end is longitudinally arranged in a row and connected to the Raman spectromete...
Embodiment 2
[0055] Embodiment 2, aiming at the spectral data measured by the system described in Embodiment 1, this embodiment proposes a method for quantitative analysis of mixed gas. After quantitative calibration of the system, the signal strength of gases with different concentrations can be obtained by measuring standard samples; for the Raman spectrum of mixed gases, this embodiment preprocesses the Raman spectrum signal, aliasing peak position decomposition method, mixed gas concentration Quantitative methods and other aspects of research, to achieve the precise quantification of the concentration of multi-component analytes in complex gas mixtures, such as image 3 shown, including the following steps:
[0056] Step A, first perform spectral preprocessing, including baseline removal, denoising, removal of abnormal points, etc.;
[0057] Step B, after processing the Raman signal, perform peak search for the Raman signal of the gas to be detected, and then perform aliasing peak dec...
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