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Electrode material of alloy element added with tungsten oxide and its preparation technique

A technology of alloying elements and electrode materials, which is applied in the field of alloying elements adding tungsten-oxide electrode materials and its preparation, can solve the problems of large oxide size, unstable arc, and low service life of electrode products, so as to reduce the loss of tungsten , increase surface tension, improve the effect of stability

Inactive Publication Date: 2004-04-28
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although my country has very rich tungsten resources and long-term research and development of tungsten oxide electrode materials, the performance of the currently produced tungsten electrodes is difficult to meet the requirements of foreign imported equipment for the use of electrodes.
The main reason is that at present, the method of adding thorium salt to tungsten oxide is used in the manufacture of tungsten electrodes in my country. The size of the oxide is large and the distribution is uneven. Moreover, this method consumes a lot of energy and causes serious pollution.
It leads to the low service life of the electrode products produced and the arc instability during use, which affects the precision and quality of plasma processing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0008] Embodiment 1, the specific technological process of the present invention is: before sintering, according to the service condition of electrode, carry out electrode component design, to reach the requirement of excellent comprehensive service performance, first add in the tungsten powder that weight ratio is 0.1% C and 5 % Nb, and 0.5% ThO2 powder, mixed evenly, cold pressed into a long billet, pre-sintered in a hydrogen environment of 1500K, and finally sintered at 2800K, and finally swaged, rolled, Wire drawing, polishing and other processes to achieve the required electrode size.

Embodiment 2

[0009] Embodiment 2, before sintering, the present invention designs the electrode composition according to the conditions of use of the electrode. First, add a mixture of 1% C, 1% V and Zr, and 1.2% CeO2 powder in the tungsten powder , After mixing evenly, it is cold-pressed into a strip-shaped billet and pre-sintered in a hydrogen environment of 1300K. Afterwards, the final sintering is carried out at 3500K, and finally the required electrode size is achieved by swaging, rolling, wire drawing, polishing and other processes.

Embodiment 3

[0010] Example 3, before sintering, the present invention designs the electrode composition according to the conditions of use of the electrode. First, add a mixture of 0.5% of C, 3% of Cr, Al and Mo, and 2.5% of After Y2O3 powder is mixed evenly, it is cold-pressed into a strip-shaped billet and pre-sintered in a hydrogen environment of 1400K. Afterwards, the final sintering is carried out at 3300K, and finally the required electrode size is achieved by swaging, rolling, wire drawing, polishing and other processes.

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Abstract

First, carbon 0.1-1% and strong oxides (1-5%) are added in the tungsten powder. Then, with one or two powders of oxides 0.5%-4% of low work function being added to the tungsten powder and mixed evenly, the admixture through chill pressing becomes the square billet is strip shape. Presintering procedure carries out at temperature 1300-1500 deg.K under hydrogen circumstance and final presintering procedures carries out at temperature 2800-3500 deg.K. The needed size of electrode is reached through the procedures of rotary swaging, rolling, wire drawing and polishing. A small quantity of alloy elements are added to the tungsten powder in order to balance the decomposition process of the oxides added in the arcing process and control the decomposition speed.

Description

1. Technical field [0001] The invention belongs to the field of novel electrical materials, and further relates to a tungsten-oxide electrode material added with alloy elements and a preparation process thereof. 2. Background technology [0002] With the development of science and technology, the preparation and processing methods of materials have made great progress. Plasma processing is a material processing method developed in recent years. Using the high temperature of plasma, metal can be melted rapidly to achieve the purposes of metallurgy, welding, cutting and surface spraying of metal materials. Arc plasma technology is widely used in industrial fields such as plasma welding, cutting, spraying, smelting and other materials preparation and processing, as well as other fields such as emitting electric light sources, microwave power tubes, vacuum tubes, and plasma thrusters. The tungsten electrode is the most critical part of these devices, which plays the role of car...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/05C22C27/04C22C32/00
Inventor 杨志懋张晖王亚平宋晓平丁秉钧
Owner XI AN JIAOTONG UNIV
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