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Atactic sulfonated high polymer containing dual diaza naphthone and synthesis and application thereof

A technology of bisdiazinone and phthalazinone, which is applied in the field of random sulfonated polymers, can solve the problems of low alcohol resistance coefficient, high preparation cost, complex synthesis route, etc., and achieve strong toughness chemical physics Performance and mechanical properties, cost-solving effects

Inactive Publication Date: 2006-12-20
SUN YAT SEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, Nafion membrane has disadvantages such as complex synthesis route, high preparation cost, low alcohol resistance coefficient, and sharp drop in proton conductivity due to water loss when the temperature is higher than 100 °C.

Method used

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  • Atactic sulfonated high polymer containing dual diaza naphthone and synthesis and application thereof
  • Atactic sulfonated high polymer containing dual diaza naphthone and synthesis and application thereof
  • Atactic sulfonated high polymer containing dual diaza naphthone and synthesis and application thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1-1

[0036] Embodiment 1-1, polymer 1aA 80 Synthesis:

[0037] With 0.627g (1mmol) bisphenol-like monomer 2a containing bisdiazinone, 0.338g (0.8mmol) sulfonated dihalogenated monomer 3A, 0.044g (0.2mmol) dihalogenated monomer 4A, 0.194g ( 1.4mmol) of anhydrous potassium carbonate, 5mLDMSO and 6mL toluene were added to a three-necked flask, under the protection of nitrogen, the temperature was raised to 150°C, kept under magnetic stirring for 2 hours, the generated water was taken out by toluene, and then the temperature was raised to 175°C, and the reaction was carried out for 20 hours, cooled, poured the reactant into 100mL methanol-water mixed solution with a volume ratio of 1:1 under constant stirring, filtered, washed three times with distilled water, and dried in vacuum at 80°C for 24 hours to obtain 0.925g of polymer 1aA 80 , yield 96%.

Embodiment 1-2

[0038] Embodiment 1-2, polymer 1aA 60 Synthesis:

[0039]With 0.627g (1mmol) bisphenol-like monomer 2a containing bisdiazinone, 0.253g (0.6mmol) sulfonated dihalogenated monomer 3A, 0.087g (0.4mmol) dihalogenated monomer 4A, 0.194g ( 1.4mmol) of anhydrous potassium carbonate, 5mLDMSO and 6mL toluene were added to a three-necked flask, under the protection of nitrogen, the temperature was raised to 150°C, kept under magnetic stirring for 2 hours, the generated water was taken out by toluene, and then the temperature was raised to 175°C, and the reaction was carried out for 20 hours, cooled, poured the reactant into 100mL methanol-water mixed solution with a volume ratio of 1:1 under constant stirring, filtered, washed three times with distilled water, and dried in vacuum at 80°C for 24 hours to obtain 0.908g of polymer 1aA 60 , yield 98%.

Embodiment 1-3

[0040] Embodiment 1-3, polymer 1aA 40 Synthesis:

[0041] With 0.627g (1mmol) bisphenol-like monomer 2a containing bisdiazinone, 0.169g (0.4mmol) sulfonated dihalogen monomer 3A, 0.131g (0.6mmol) dihalogen monomer 4A, 0.194g ( 1.4mmol) of anhydrous potassium carbonate, 5mLDMSO and 6mL toluene were added to a three-necked flask, under the protection of nitrogen, the temperature was raised to 150°C, kept under magnetic stirring for 2 hours, the generated water was taken out by toluene, and then the temperature was raised to 175°C, and the reaction was carried out for 20 hours, cooled, poured the reactant into 100mL methanol-water mixed solution with a volume ratio of 1:1 under constant stirring, filtered, washed three times with distilled water, and vacuum-dried at 80°C for 24 hours to obtain 0.825g of polymer 1aA 80 , yield 93%.

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Abstract

A sulfonated atactic high polymer containing double biazanaphthone is prepared through copolymerizing reaction between biphenol containing double biazanaphthone, sulfonated dihalgoen and dihalogen in the polar nojn-protonic solvent under the action of potassium carbonate. It can be used to prepare the proton exchange membrane with low cost, and high mechanical strength, hydroscopicity, stability and proton exchange capacity.

Description

technical field [0001] The invention relates to a kind of random sulfonated high polymer containing bisdiazinone and its synthesis and application. technical background [0002] With the continuous consumption and depletion of conventional energy sources, and also based on concerns about the continuous deterioration of the environment, researchers and developers from all over the world are turning their attention to more efficient and cleaner use of energy research. Fuel cells have the advantages of high energy conversion efficiency (40-60%), no pollution, and no noise, and will become the preferred energy supply method in the 21st century. At present, the fuel cell has been developed to the fifth generation, that is, the Proton Exchange Membrane Fuel Cell (PEMFC). In addition to the advantages of the general fuel cell, it is also portable, can be quickly started at room temperature, and has no electrolysis. Liquid loss, long life, high specific power and specific energy. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G73/06H01M8/02H01M8/102H01M8/1069
CPCY02E60/50
Inventor 孟跃中陈玉林肖敏王雷王拴紧
Owner SUN YAT SEN UNIV
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