The invention belongs to the technical field of
lithium ion batteries, and discloses a polyquinoneimidazole-based covalent
organic polymer material, a preparation method thereof and an application of the polyquinoneimidazole-based covalent
organic polymer material in a
lithium ion battery negative
electrode material. The preparation method comprises the following steps: carrying out a
hydrothermal synthesis reaction on hexaaza-
naphthalene carboxylic acid (HAT-6COOH) and tetraamino p-
benzoquinone (TABQ) or 2, 3, 7, 8-tetraamino-1, 4, 6, 9-tetraquinone
phenazine (TAPT) to prepare two kinds of polyquinoneimidazole
organic polymer materials, and respectively recording the two kinds of polyquinoneimidazole organic
polymer materials as HATTABQ and HATTAPT. The
lithium ion battery based on the material disclosed by the invention shows relatively high specific capacity and relatively good cycle stability. Under the
current density of 10 A / g, the HATTABQ
electrode can reach the
specific discharge capacity of 279.2 mAh / g in the first circle, the HATTABQ
electrode can stably circulate for 20000 circles, and the capacity
retention ratio is 78.4%. Under the
current density of 5A / g, the HATTAPT electrode can reach the
specific discharge capacity of 473.8 mAh / g in the first circle, the HATTAPT electrode can be stably circulated for 2000 circles, and the capacity
retention ratio is 64.3%. The preparation method is simple in process and beneficial to large-scale industrial production, and has potential application value in
lithium ion battery negative electrode materials.