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169 results about "Naphthalene Derivative" patented technology

Fluorescent probe reagent for concurrent selection and determination of multiple metal ions, and preparation and appliance

The invention discloses a probe reagent for concurrent selection and determination of multiple metal ions, and preparation and appliance, and belongs to the field of organic synthesis and analytical chemistry. Tri (2-aminoethyl) amine serves as a parent, wherein rhodamine B is connected to an amino chain, 2-hydroxy-1-naphthaldehyde groups are connected to other two amino chains respectively, and thus a tripod structured rhodamine-hydroxyl naphthalene derivative probe is prepared. In 1,4-dioxane/water (19/1, v/v, pH=7) solution, the probe respectively detects Cu2+, Co2+ and Fe3+ by utilizing rate absorption of different wavelengths, and the detection does not interfere with each other; in acetonitrile/water (19/1, v/v) solution, fluorescence emission of different wavelengths under different pHs is utilized, the probe respectively detects Zn2+, Al3+, Hg2+ and Cu2+, and the detection does not interfere with each other; under an ultraviolet lamp of 365 nm, Zn2+, Al3+ and Hg2+ are detected to show blue, pink and orange red fluorescence respectively, and through -Zn2+ mixture detection by the probe, Cu2+ shows blue fluorescence vanishing. The probe structure is as follows.
Owner:GUIZHOU UNIV

Perylene derivative synthesis process, perylene derivative and organic EL device

The invention aims to provide a perylene derivative preparation process featuring satisfactory yields and improved preparation efficiency, a perylene derivative obtained by the process, and an organic EL device using the same. The object is achieved by a perylene derivative preparation process comprising subjecting to coupling reaction a 1,8-dihalogenated naphthalene derivative of the formula (1): wherein X is Cl, Br or I, R1 to R4, R11 and R12 each are hydrogen, alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio, aralkyl, aralkyloxy, aralkylthio, aryl, aryloxy, and arylthio radicals which may be substituted, amino radical, cyano radical, hydroxyl radical, —COOM1 radical (wherein M1 is hydrogen, alkyl, alkenyl, aralkyl or aryl), —COM2 radical (wherein M2 is hydrogen, alkyl, alkenyl, aralkyl, aryl or amino), or —OCOM3 radical (wherein M3 is alkyl, alkenyl, aralkyl or aryl), and at least two adjoining radicals selected from among R1 to R4, R11 and R12 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms on which they substitute, with the proviso that when the carbocyclic aliphatic ring, aromatic ring or fused aromatic ring has substituent radicals, the substituent radicals are the same as R1 to R4, R11 and R12, to thereby synthesize a perylene derivative of the formula (2): wherein R1′ to R4′, R11′ and R12′ are as defined for R1 to R4, R11 and R12 in formula (1), and R1 to R4, R11 and R12 and R1′ to R4′, R11′ and R12′ may be the same or different.
Owner:FUTABA CORPORATION

Iridium complex phosphorescent materials with wavelengths from infrared to near-infrared range and preparation method thereof

The invention relates to a class of phosphorescent iridium complexes with wavelengths from infrared to near-infrared range, particularly relates to a class of bicyclo metal iridium complexes (C^N)2Ir(L^Y) and ionic metal iridium complexes (C^N)2Ir(N^N)<+>Z<->, with structures represented by formula (I) and formula (II) respectively, wherein R1 and R2 are independently one of hydrogen atom, halogen atom, cyan group, nitro group, acyl group, C1-18 linear chain, branched chain or cyclic aliphatic alkyl group, substituted alkyl group, alkoxy group, aryloxy, alkylthio group, arylthio, aliphatic amine group, aromatic amine group, substituted siloxane group, substituted silicon group, aryl group, substituted aryl group, heterocyclic aryl group or substituted heterocyclic aryl group; C^N is a phenylquinoline substituted naphthalene derivative; L^Y is one of N-COOH, 8-hydroxyquinolines, beta-diketones, N^NH and other compounds; N^N is one of dipyridine, diquinoline, 1,10-o-phenanthroline and derivatives thereof and other compounds; and Z is hexafluorophosphate radical or perchlorate radical. The bicyclo metal iridium complexes (C^N)2Ir(L^Y) are shown in formula (I), and the ionic metal iridium complexes (C^N)2Ir(N^N)<+>Z<-> are shown in formula (II).
Owner:NANJING UNIV OF POSTS & TELECOMM
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