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Sealing material for electrochemical element and electrochemical element contg. same

A technology of electrochemical components and sealants, applied in the field of electrochemical components, can solve the problems of uneven sealing of sealants and the like

Inactive Publication Date: 2003-08-13
PANASONIC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the sealant has different sealant thickness, the sealing performance will be different, so the uneven thickness of the sealant provided on the sealing part will make the sealability also uneven.

Method used

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  • Sealing material for electrochemical element and electrochemical element contg. same
  • Sealing material for electrochemical element and electrochemical element contg. same
  • Sealing material for electrochemical element and electrochemical element contg. same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] image 3 It is a longitudinal sectional view of a flat manganese dioxide / lithium battery with a thickness of 0.5 mm and a diameter of 20 mm manufactured in this example.

[0052] image 3 A state where the gasket 6 and the metal case 1 and between the gasket 6 and the sealing plate 5 are sealed with a sealant is shown. image 3 , the metal case is made of 0.1mm thick stainless steel plate and also has a positive terminal. The inner surface of the metal shell 1 is in contact with the positive electrode 2, and the positive electrode 2 is made of 0.18 mm thick pellets formed by pressure molding of mixed powder of manganese dioxide, graphite and binder. The upper surface of the positive electrode 2 was covered with a separator 3 made of a porous polypropylene sheet with a thickness of 0.03 mm. A negative electrode 4 made of metallic lithium with a thickness of 0.06 mm is provided opposite to the positive electrode 2 via a separator 3 . The negative electrode 4 is attach...

Embodiment 2

[0056] A battery was produced in the same manner as in Example 1, except for using a sealant mixed with 100 parts by weight of polyisobutylene having a viscosity average molecular weight of 900,000 and 30 parts by weight of the same tackifier as in Example 1. b.

Embodiment 3

[0075] Batteries were produced in the same manner as in Example 1, except that the amount of tackifier contained in the sealant was varied from 3 to 175 parts by weight per 100 parts by weight of butyl rubber shown in Table 3. However, a terpene-based resin (Picolite A-115 manufactured by Haikicores Co., Ltd.) was used as a thickener.

[0076] Using 10 of the obtained batteries, a thermal cycle test in which the batteries were periodically exposed to temperatures ranging from -20°C to +60°C was carried out, and the number of batteries in which liquid leakage occurred was checked after 250 cycles. The results are listed in Table 3.

[0077] Amount of tackifier added (weight)

[0078] In Table 3, for the batteries added with 3-150 parts by weight of tackifier per 100 parts by weight of butyl rubber, almost no liquid leakage was found in the heat cycle test. This may be because the elastic modulus of the sealant is lowered by adding the above-mentioned amount of tackif...

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Abstract

A sealing material for electrochemical elements which comprises a rubber ingredient and a tackifier and keeps the electrochemical elements in a highly sealed state in a wide temperature range, wherein the rubber ingredient comprises at least either of butyl rubber and polyisobutylene rubber and the tackifier comprises at least one member selected from the group consisting of terpene resins, aliphatic petroleum resins, and alicyclic petroleum resins.

Description

technical field [0001] The present invention relates to a sealing compound for electrochemical elements utilizing electrochemical reactions such as batteries, electric double layer capacitors, and aluminum electrolytic capacitors. The invention also relates to electrochemical components with good hermeticity over a wide temperature range. Background technique [0002] Most electrochemical elements have an element unit (unit) composed of a pair of electrodes facing each other across a separator, an electrolytic solution, and a container for accommodating them. Usually, a container is composed of a bottomed metal case having an opening, and a sealing body that seals the opening. The shapes of the metal shell include: bottomed cylinder, square, button and so on. An electrically insulating gasket (gasket) is provided between the metal shell and the sealing body. A sealant can be used to seal between the opening end of the metal case and the sealing body, between the opening e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/00H01G9/10H01G11/00H01G11/54H01G11/62H01G11/78H01G11/80H01M6/40H01M6/42H01M10/04H01M50/186H01M50/193H01M50/417
CPCH01M2/1686H01M10/0525Y02E60/13H01M6/42H01M10/0585H01G9/155H01M10/04H01M2300/0085H01M2/1653H01M2/08H01M10/0565H01M6/40H01M2/166Y02E60/122H01G9/10Y02E60/10H01M50/446Y02P70/50H01G11/52H01G11/56H01G11/12H01M50/417H01M50/186H01M50/193
Inventor 宇山孝男冈久贡池畠敏彦山中晋冈本俊英佐藤滋记田中义宪坪田富久治
Owner PANASONIC CORP