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C6 recycle for propylene generation in a fluid catalytic cracking unit

A fluidized catalysis, propylene technology, applied in catalytic cracking, cracking, hydrocarbon cracking to produce hydrocarbons, etc., can solve the problems of low olefin selectivity and increased cost of light olefins, etc.

Active Publication Date: 2006-04-05
EXXON RES & ENG CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Additionally, even though a specific catalyst balance can be maintained to maximize overall olefin production relative to fuel, olefin selectivity is often low due to undesired side reactions such as extensive cracking, isomerization, aromatization, and hydrogen transfer reactions
Increased cost of recovering the desired light olefins due to the production of light saturated gases from undesired side reactions

Method used

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  • C6 recycle for propylene generation in a fluid catalytic cracking unit
  • C6 recycle for propylene generation in a fluid catalytic cracking unit

Examples

Experimental program
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Embodiment 1

[0042] Trials were conducted using three different streams of an FCC plant producing propylene. The three streams are Cat gasoline fraction A (light cat gasoline fraction), Cat gasoline fraction B (heavy Cat gasoline fraction) and Cat gasoline fraction (C-rich gasoline fraction). 6 catalytic gasoline fraction). A portion of the FCC naphtha stream was recirculated and injected upstream of the main feed injector. Table 1 shows the results for three different streams. figure 1 Propylene selectivities from data in Table 1 are shown. The average propylene selectivity was 0.62 for Cat Naphtha Fraction C, 0.37 for Cat Naphtha Fraction A and 0.29 for Cat Naphtha Fraction B. figure 2 Propylene yields when naphtha was recycled from data in Table 1. Propylene yields averaged 9.5% by weight for Cat. gasoline fraction C, 6.0% by weight for Cat. gasoline fraction A and 5.1% by weight for Cat. gasoline fraction B while recycle naphtha.

[0043] catalytic gasoline

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Abstract

The present invention relates to a process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream. The process is practiced by recycling a C6 rich fraction of the catalytic naphtha product to the riser upstream the feed injection point, to a parallel riser, to the spent catalyst stripper, and / or to the reactor dilute phase immediately above the stripper.

Description

field of invention [0001] The present invention relates to the selective production of C from catalytically cracked or thermally cracked naphtha streams in a fluidized bed catalytic process unit 3 Alkenes method. By converting the C-rich product of the catalytic naphtha 6 The process is carried out by recycling the fraction to a riser upstream of the feed injection point, a riser downstream of the feed injection point, a parallel riser, a spent catalyst stripper, and / or a reactor dilute phase immediately above the stripper. Background of the invention [0002] The need for low emission fuels has created an increased demand for light olefins used in the alkylation, oligomerization, methyl tert-butyl ether and ETBE synthesis processes. In addition, there is a continuing need for the low-cost supply of light olefins, especially propylene, as feedstock for the production of polyolefins, especially polypropylene. [0003] Fixed bed processes for the dehydrogenation of light al...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G11/05C10G11/18C07C4/02C10G11/00
CPCC10G2300/4081C10G11/05C10G11/18C10G2300/1044C10G2400/20C10G2300/4093
Inventor 陈诞仁布赖恩·埃里克·亨利保罗·F·科伊森科滕菲利普·A·鲁日斯科
Owner EXXON RES & ENG CO
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