Gel materials, medical articles, and methods
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[0097] The following examples are offered to aid in understanding of the present invention and are not to be construed as limiting the scope thereof. Unless otherwise indicated, all parts and percentages are by weight.
[0098] The following Preparative Examples are directed toward preparing macromonomers of the formula
XO—(—CH(R1)—CH2—O—)m . . . (—CH2—CH2—O—)n—Y
[0099] wherein X and Y are each independently selected from the group consisting of
AcronymXYR1R2R3m:nWrMAA-PEGStructure 1Structure 1CH3CH3—1:3——VAZ-PEGStructure 3Structure 3CH3——1:3——IEM-PEGStructure 2Structure 2CH3CH3—1:3—2IPH1-PEGStructure 4Structure 4CH3CH3Isophorone1:3(CH2)2—IPH2-PEGStructure 4Structure 4CH3CH3Isophorone1:3(CH2)2—IPH3-PEGStructure 4Structure 4CH3CH3Isophorone1:3(CH2)2—TDI-PEGStructure 4Structure 4CH3CH3Tolylene1:3(CH2)2—PIA-IPDI-Structure 5Structure 5CH3—Isophorone1:3——PEG
Preparative Examples
[0100] Preparation of methacrylated polyalkylene oxide (MAA-PEG). A mixture of 218.15 grams (g) of poly(ethylene...
examples 1-3
Preparation of Absorbent Films
Example 1
[0112] A mixture of 99.8 g of the macromonomer MAA-PEG and 0.20 g. of IRGACURE 2959 photoinitiator (Ciba Specialty Chemical Corp., Tarrytown, N.Y.) were mixed on a roller for 24 hours then cured between two polyester release liners under UV light at a total dose of 2100 mJ / cm2. The resulting polymer film was 1.1 mm thick when removed from the polyester release liners.
example 2
[0113] Example 2 was prepared as in Example 1 with macromonomer VAZ-PEG used instead of MAA-PEG.
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