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Ultra low phosphorus lubricant composition

a lubricant composition and low phosphorus technology, applied in the direction of additives, lubricant compositions, liquid carbonaceous fuels, etc., can solve the problems of affecting the performance vehicles emit high levels of pollution, and fouling of pollution control devices, etc., to achieve excellent fuel economy, low phosphorus content, and high molybedenum

Inactive Publication Date: 2014-08-14
VANDERBILT CHEM LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent describes a new lubricant that has many benefits. It helps reduce friction, prevents wear and corrosion, and also reduces the amount of phosphorus that is released into the atmosphere. This makes it great for use in engines, which can help increase fuel economy and protect against damage while running.

Problems solved by technology

Unfortunately, many of these additives contribute to the fouling of the pollution control devices.
When this occurs, vehicles emit high levels of pollution because of the failing performance of the pollution control devices.
It has been determined that high levels of phosphorus, sulfur and ash in gasoline and diesel engine oils can negatively affect the performance of pollution control devices.
Not only is the level of phosphorus in engine oil important for the proper performance of pollution control devices but also phosphorus volatility.
Phosphorous volatility can have a significant negative impact on the performance of pollution control devices.
Unfortunately, the antiwear additives used in engine oils to protect the engine contain sulfur and phosphorus.
However, it is also well known that high levels of molybdenum in engine oil can cause engine corrosion and wear.

Method used

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  • Ultra low phosphorus lubricant composition
  • Ultra low phosphorus lubricant composition
  • Ultra low phosphorus lubricant composition

Examples

Experimental program
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Effect test

Embodiment Construction

(1) Organomolybdenum Compound

[0016]A preferred organomolybdenum compound is prepared by reacting about 1 mole of fatty oil, about 1.0 to 2.5 moles of diethanolamine and a molybdenum source sufficient to yield about 0.1 to 12.0 percent of molybdenum based on the weight of the complex at elevated temperatures (i.e. greater than room temperature). A temperature range of about 70° to 160° C. is considered to be an example of an embodiment of the invention. The organomolybdenum component of the invention is prepared by sequentially reacting fatty oil, diethanolamine and a molybdenum source by the condensation method described in U.S. Pat. No. 4,889,647, incorporated herein by reference, and is commercially available from R.T. Vanderbilt Company, Inc. of Norwalk, Conn. as Molyvan® 855. The reaction yields a reaction product mixture. The major components are believed to have the structural formulae:

wherein R′ represents a fatty oil residue. An embodiment for the present invention are fatty...

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Abstract

A low-phosphorus lubrication composition has less than 600 ppm phosphorus, comprising at least 85 weight % of a lubricating base blend, and an additive comprising the following, as weight % of the total composition:(1) an organomolybdenum compound at an amount which provides about 0.1-800 ppm Mo;(2) a hindered phenol at about 0.1-2%; and(3) a dithiocarbamate at about 0.1-2%;with a first proviso that where the dithiocarbamate does not comprise a metal dithiocarbamate, the additive additionally comprises:(4) an alkylated diphenylamine at about 0.1-2%,and with a second proviso that where the organomolybdenum compound comprises molybdenum dithiocarbamate, it is considered a metal dithiocarbamate for purposes of the first proviso, but is considered an organomolybdenum compound for the purposes of calculation of the amount present in the total composition.

Description

[0001]This application is a continuation of U.S. patent application Ser. No. 13 / 071,785, filed Mar. 25, 2011, which claims priority of U.S. Provisional Application No. 61 / 317,499, filed Mar. 25, 2010.BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0003]The invention concerns additive compositions and lubricating compositions for use in a low phosphorus environment, which provide excellent phosphorus retention and improved resistance to lead and copper corrosion.[0004]2. Discussion of the Prior Art[0005]Government regulations over the last several decades have required Original Equipment Manufacturers (OEMs) to improve fuel economy and reduce pollution emissions for gasoline and diesel powered vehicles. It is common knowledge that OEMs and lubricant companies expect government to mandate even stricter fuel economy and emission requirements in the future. Many, if not all, of the vehicles now on the road contain pollution control devices to reduce pollution.[0006]Engine oil...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10M141/12
CPCC10M141/12C10M2207/044C10M2207/284C10M2215/064C10M2219/066C10M2219/068C10M2223/045C10M141/10C10M2207/026C10M2207/289C10M2215/223C10M2227/09C10N2010/12C10N2030/38C10N2030/42C10N2030/08C10N2030/54C10N2030/06C10N2010/04C10N2030/12C10N2040/25C10M2215/22C10M141/06C10M141/08C10M2207/144
Inventor MAZZAMARO, GLENN A.DONNELLY, STEVEN G.HIZA, RONALD J.
Owner VANDERBILT CHEM LLC
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