The present disclosure relates to polyquinoxalines containing basic groups, which are obtained by copolymerization of a dioxinone
monomer and a
tetramine monomer. The present disclosure also relates to
proton exchange membranes formed from the polyquinoxalines containing basic groups. The polyquinoxalines containing basic groups provided by the present disclosure have excellent
mechanical strength,
thermal stability,
chemical stability and
phosphoric acid doping rate, while having site-controllable basic groups, and have broad application prospects.