The invention provides a graphene conductive powder coating before wooden product coating as well as preparation and application thereof. The conductive powder coating is composed of the following components: epoxy resin, graphene, a dispersing agent, a filler, a silane coupling agent, a coupling agent of organic titanate, a flatting agent, a curing agent, an antifoaming agent and the like. The conductive powder coating can be applied to conductive treatment before wooden product coating, and the wooden product is treated and dried and cured to form a flat and dense conductive coating on the surface. The conductive powder coating is capable of closing pores on the surface of the wooden product base material and does not diffuse and permeate on the surface, so that the conductivity performance on the surface of the base material is improved, the electrostatic spraying coating quality of the wooden product is improved, phenomena such as pinholes, bubbles and cracking occurring in the coating flatting and curing process are avoided, and the adhesive force between the wooden product base material and the coating is promoted. The graphene conductive powder coating is excellent in hardness and resistance, is capable of improving the durability of the wooden products and can be widely applied to coating treatment industries of the wooden products.