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Organosilane compounds for modifying dielectrical properties of silicon oxide and silicon nitride films

一种氧化硅膜、氮化硅膜的技术,应用在电路、电气元件、气态化学镀覆等方向,能够解决没有提供支持等问题

Inactive Publication Date: 2013-10-30
VERSUM MATERIALS US LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the application suggests the feasibility of these precursors, it does not provide experimental data to support that films can be prepared from these precursors in a manner that addresses the cost-of-ownership that needs to be exploited in the manufacture of integrated circuits
Additionally, there may be issues related to safe handling and substance use

Method used

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  • Organosilane compounds for modifying dielectrical properties of silicon oxide and silicon nitride films
  • Organosilane compounds for modifying dielectrical properties of silicon oxide and silicon nitride films
  • Organosilane compounds for modifying dielectrical properties of silicon oxide and silicon nitride films

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Embodiment 1 adopts LPCVD method to prepare SiO from BTBAS 2 standard method. This example serves as a baseline for other data.

[0065] Examples 2-5 are data supporting the first method of the present invention, which is the production of modified silica by using a combination of an organosilane-containing precursor and an oxygen source.

[0066] Examples 6-9 are data supporting the second method of the present invention, the modification of silicon oxide or silicon nitride by carbon doping. More specifically, methods of depositing modified silicon oxides or silicon nitrides using existing precursor chemistries, such as BTBAS, doped with organosilanes (containing carbon), such as phenylsilanes. The advantage of this method is that the membranes are derived from already used chemicals. Thus, fewer device and method problems need to be dealt with than if entirely new chemicals were used. Furthermore, by varying the ratio of the two chemicals present in the formulatio...

Embodiment 2

[0072] Example 2: Deposition of silicon oxide from phenylsilane

[0073] The process condition of this embodiment is:

[0074] LPCVD deposition, temperature range from 400°C to 500°C, pressure 600mtorr, precursor (phenylsilane):O 2 The current ratio is from 2:1 to 4:1. Table 2 shows the results.

[0075] Deposition temperature (°C) Precursor: O 2 Refractive index Dielectric constant 1% wet etch rate 400 3∶1 1.5311 not measured 0.10 450 4∶1 1.5163 3.81 0.16 500 2∶1 1.5117 4.12 0.56

Embodiment 3

[0076] Example 3: Deposition of silicon oxide from tetravinylsilane

[0077] The process condition of this embodiment is:

[0078] LPCVD deposition, temperature range from 500°C to 600°C, pressure range from 600mtorr to 1torr pressure, precursor (tetravinylsilane):O 2 The current ratio is from 1:1 to 1:2. Table 3 shows the results.

[0079] table 3

[0080]

[0081] ND: No etch rate detected, assumed to be

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Abstract

The present invention discloses a process for depositing a carbon containing silicon oxide film, or a carbon containing silicon nitride film having enhanced etch resistance. The process comprises using a silicon containing precursor, a carbon containing precursor and a chemical modifier. The present invention also discloses a process for depositing a silicon oxide film, or silicon nitride film having enhanced etch resistance comprising using an organosilane precursor and a chemical modifier.

Description

[0001] Cross References to Related Applications [0002] This application claims the benefit of US Provisional Application No. 60 / 861,327, filed November 28, 2006. The disclosure of this provisional application is incorporated herein by reference. Background technique [0003] Silicon oxide films are used for a variety of applications in the fabrication of transistor structures for integrated circuits. These applications include use as hardmasks for ion implantation, etch stops to control contact hole etching, sidewall partition films along gates, protective films to shield adjacent species from etching or cleaning processes, Environmental barriers, and dielectric substances to reduce external fringe capacitance. To address these many demands, tailoring the chemical and physical properties of these membranes is necessary. [0004] Lower temperature methods for the preparation of silicon oxide and silicon nitride have been developed using chemical precursors such as hexachlo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C16/22C23C16/30C23C16/40C23C16/34
CPCH01L21/31633H01L21/3121H01L21/02211H01L21/02126H01L21/0217H01L21/02271H01L21/02164H01L21/3185C23C16/401C23C16/345C23C16/42C23C16/00H01L21/20
Inventor 萧满超H·斯里丹达姆E·J·小卡瓦基雷新建
Owner VERSUM MATERIALS US LLC
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