Tunable selectivity slurries in cmp applications
A mechanical polishing, selective technology, applied in other chemical processes, chemical instruments and methods, polishing compositions containing abrasives, etc., can solve problems such as erosion
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[0046] This example illustrates the tunable selectivity obtained by the method of the invention.
[0047] The first chemical-mechanical polishing composition contained 5% by weight of polycondensed silica (Nalco TX11005) with an average primary particle size of 25 nm, 0.0837% by weight of iron nitrate, 69 ppm malonic acid, and 1250 ppm tetrabutylammonium hydroxide ( TBAH). The first chemical-mechanical polishing composition exhibited a high removal rate for tungsten, ie, 2700 angstroms / minute. The second chemical-mechanical polishing composition contained 5% by weight of polycondensed silica (Nalco TX11005) with an average particle diameter of 25 nm and 1250 ppm of TBAH. The second chemical-mechanical polishing composition exhibited a high removal rate for oxide, ie, 1900 angstroms / minute. The first and second polishing compositions were mixed in various proportions, and 4% by weight hydrogen peroxide was added to produce 7 polishing compositions (1A, 1B, 1C, 1D, 1E, 1F, and...
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