Composite rotating disk liquid film reactor and method for processing organic wastewater

A technology of liquid film reactor and organic wastewater, applied in the direction of light water/sewage treatment, etc., can solve the problems of complex structure of double turntable, easy corrosion of stainless steel, no contribution to wastewater treatment, etc., to overcome easy corrosion by acid solution, simplify Reaction device, effect of improving degradation efficiency

Inactive Publication Date: 2010-07-14
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its shortcoming is that the cathode in the device is static, and the photogenerated electrons are still transferred by the anode bias, and the electrons are not effectively utilized after being transferred to the cathode, and do not contribute to the treatment of wastewater.
However, the structure of the double rotating disk of the reactor is relatively complicated. The anode base made of titanium has good stability but high cost, and the cost of the anode base made of stainless steel is low, but it is easily corroded under the optimal reaction conditions, namely acidic conditions.

Method used

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  • Composite rotating disk liquid film reactor and method for processing organic wastewater
  • Composite rotating disk liquid film reactor and method for processing organic wastewater
  • Composite rotating disk liquid film reactor and method for processing organic wastewater

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Treatment of Dye Wastewater by TiO2 / Stainless Steel / Cu Composite Rotary Disk Liquid Film Reactor

[0028] Such as figure 1 and figure 2 As shown, the treatment object is 50mg / L reactive brilliant red X-3B (pH 2.50, 1.0g / L Na 2 SO 4 ) to simulate dye wastewater, the volume of wastewater is 50mL.

[0029] Using stainless steel disks as substrates, TiO 2 The photocatalyst is loaded on the substrate, and Cu is electroplated on the other side of the substrate by EDTA method to form TiO 2 / Stainless steel / Cu composite turntable, the composite turntable is fixed on the rotating shaft and connected with the motor.

[0030] The composite turntable is placed in the semi-arc reaction tank, the rotating shaft of the composite turntable is at the water surface of the wastewater, so that the lower half of the composite turntable is submerged in the wastewater.

[0031] Start the motor, and control the rotation speed of the composite turntable to 90 rpm through the governor, so...

Embodiment 2

[0038] TiO 2 / Ti / Cu Composite Rotary Disk Liquid Film Reactor for Dye Wastewater Treatment

[0039] The treatment object is 50mg / L Reactive Brilliant Red X-3B (pH 2.50, 1.0 g / L Na 2 SO 4 ) to simulate dye wastewater. The waste water volume is 50mL.

[0040] Step is with embodiment 1, and wherein metal substrate is Ti substrate, and the waste water treatment time is 1 hour, asks decolorization rate (%), and result is as follows:

[0041] time (min)

[0042] It can be seen that Ti can also be used as the metal substrate of this reactor, and satisfactory results can be obtained after 1 hour of treatment.

Embodiment 3

[0044] TiO 2 / Stainless steel / Cu composite turntable liquid film reactor for treating dye wastewater with different pH values

[0045] The treatment object is 50mg / L Reactive Brilliant Red X-3B (1.0g / L Na 2 SO 4 ) to simulate dye wastewater. The waste water volume is 50mL.

[0046] Step is with embodiment 1, asks decolorization rate (%), and result is as follows:

[0047] The pH value of Reactive Brilliant Red X-3B

[0048] It can be seen that the TiO2 / stainless steel / Cu composite rotating disk liquid membrane reactor has the best effect in treating dye wastewater under the acidic condition of pH 2.50. In the structure of the composite turntable, the cathode Cu can block the direct contact between the stainless steel substrate and the solution, preventing it from being corroded by the acid solution.

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PUM

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Abstract

The invention relates to a composite rotating disk liquid film reactor and a method for processing organic wastewater in the technical field of chemical industry. The composite rotating disk liquid film reactor comprises a speed regulator, a motor, a composite rotating disk, a reaction pool and a light source, wherein the speed regulator is connected with the motor to carry out speed regulation; the center of the composite rotating disk is fixedly arranged at the output end of the motor; the composite rotating disk is positioned in the reaction pool and is in contact with the liquid to be detected in the reaction pool; the lower half part of the composite rotating disk is soaked in a solution of the reaction pool, and the upper half part is arranged in the air; and the light source is horizontally arranged at one side of a titanium dioxide anode and is at the same height with an axle center of the composite rotating disk. A TiO2 light anode is illuminated by an excitation light sourceso that excitation light is illuminated on the surface of TiO2 catalyst by a wastewater liquid film; by sampling analysis after standing for 0.5-2 hours, the moving rate of an organic matter in the wastewater is detected, and the processing of the organic wastewater is finished. The invention compounds a cathode and an anode of a double-rotating disk into a whole when improving the photocatalysisefficiency and reducing the energy consumption, covers a metal substrate with cathode copper and blocks the direct contact between the metal substrate and the wastewater.

Description

technical field [0001] The invention relates to a reactor in the technical field of chemical industry and a method for treating wastewater thereof, in particular to a compound rotary disk liquid film reactor and a method for treating organic wastewater. Background technique [0002] In recent years, TiO 2 It has been proven to be a highly efficient, stable, non-selective and readily available semiconductor photocatalyst. TiO 2 As an advanced oxidation technology, photocatalytic technology can almost completely mineralize air and water pollutants without secondary pollution, and the reaction conditions are mild. It has become an attractive method for organic pollution treatment. Since Fujishima discovered TiO in 1972 2 Since the photocatalytic splitting of water, TiO 2 Semiconductor photocatalysis technology has gradually been extensively studied in the treatment of organic matter. To solve TiO 2 Difficult to separate from wastewater, TiO 2 are immobilized on various s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/30C02F1/32
Inventor 贾金平柳贤莉王亚林徐云兰李侃
Owner SHANGHAI JIAO TONG UNIV
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