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Semisteel steelmaking slagging method aided by utilizing burn-in tailings

A steelmaking slagging agent and tailings technology, which is applied in the field of semi-steel steelmaking, can solve the problems of aggravated furnace lining erosion, short duration, unfavorable environmental protection, etc., and achieve the goals of shortening the initial slag formation time, lowering the melting point, and saving energy consumption Effect

Active Publication Date: 2012-02-22
HEBEI IRON AND STEEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, semi-steel making and slagging mainly rely on the iron in the molten metal to form iron oxide to promote lime melting during the blowing process of semi-steel making and steelmaking, which makes it difficult to make slagging during the blowing process.
In order to solve this problem, fluorite is usually added as a slagging agent to assist slagging in the slagging process. The amount added is generally 4-6kg / t steel. Adding fluorite can significantly reduce the melting point of CaO, 2CaO.SiO2 and the viscosity of slag. To achieve the purpose of rapid slagging, but there are problems such as short duration, easy to return to dryness, large-scale use will increase splashing, and aggravate the erosion of the furnace lining.
In addition, since the main component of fluorite is CaF2, the production process is not conducive to environmental protection

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] For the production of steel type HRB335, 112 tons of semi-steel are loaded into the converter, [C] 3.74%, [S] 0.038%, [P] 0.085% in the semi-steel, the temperature is 1368°C, and the steel output of this furnace is 105 tons; The target temperature of HRB335 blowing end point is 1670℃, [C]0.05-0.15%, [S]≤0.040%, [P]≤0.035%. When blowing starts, add lime at 30kg / t steel (5kg / t steel less than the normal amount), add dolomite at 15kg / t steel, and add machine-burned tailings at 5.0kg / t steel. The slagging time in the early stage of blowing is At 211 seconds, the slag was sampled 1 minute after the initial slag was formed, and the basicity was 3.03; the phosphorus distribution ratio was 59, and the TFe content was 23%. Add lime 2000kg (1000kg each time) in two batches when blowing reaches 6-7 minutes. In the middle stage of converter blowing (8 minutes of oxygen supply), the sonar slag analyzer shows that the process is dry, and the instantaneous oxygen supply is reduced fr...

Embodiment 2

[0028]Production of steel grade 45, 118 tons of semi-steel into the converter, [C] 3.82%, [S] 0.045%, [P] 0.095% in the semi-steel, the temperature is 1374°C, and the steel output of this furnace is 108 tons; Species 45 requires a blowing end point temperature of 1630-1645°C, [C]0.10-0.20%, [S]≤0.025%, and [P]≤0.015%. When blowing starts, add lime at 35kg / t steel (5kg / t steel less than the normal amount), add dolomite at 18kg / t steel, and add machine-burned tailings at 7.8kg / t steel. The slagging time in the early stage of blowing is At 174 seconds, the slag was sampled after 1 minute of initial slag formation, and the basicity was 3.33; the phosphorus distribution ratio was 76, and the TFe content was 24%. Add lime 2000kg (1000kg each time) in two batches when blowing reaches 5-6 minutes. In the middle stage of converter blowing (when oxygen is supplied for 7 minutes), the sonar slag analyzer shows that the process is back dry, and the instantaneous oxygen supply is reduced ...

Embodiment 3

[0030] For the production of steel grade ER70S-6, 115 tons of semi-steel are loaded into the converter, [C] 3.84%, [S] 0.042%, and [P] 0.088% in the semi-steel, the temperature is 1368°C, and the tapping volume of this furnace is 106 tons ; Steel ER70S-6 blowing end point requires a temperature of 1640-1665 ° C, [C] 0.04-0.09%, [S] ≤ 0.025%, [P] ≤ 0.010%. When blowing starts, add lime at 45kg / t steel (5kg / t steel less than the normal amount), add dolomite at 23kg / t steel, and add machine-burned tailings at 10kg / t steel. The slagging time in the early stage of blowing is 168 Second, the slag was sampled after 1 minute of initial slag formation, the basicity was 3.44; the phosphorus distribution ratio was 93, and the TFe content was 23%. Add lime 800kg when blowing reaches 5 minutes. In the middle stage of converter blowing (when oxygen is supplied for 7 minutes), the sonar slag analyzer shows that the process is back to dry, and the instantaneous oxygen supply is reduced from ...

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Abstract

The invention relates to a semisteel steelmaking slagging method aided by utilizing burn-in tailings, belonging to the technical field of metallurgical steelmaking and solving the problem of semisteel steelmaking slagging difficulty. The method comprises the following steps of: recovering the burn-in tailings generated in a sintering process; screening out the burn-in tailings with the granularity of 5-30mm as a semisteel steelmaking slagging agent; and adding the burn-in tailings to a converter to aid rapid slagging at the primary blowing stage according to a speed of 5-10kg / t in 0-2 min after blowing is started during semisteel steelmaking. Compared with the prior art, the invention has the advantages of: (1) shortening the primary slagging time, accelerating the melting of semisteel steelmaking lime and shortening the time about 33s on average than a traditional process; (2) improving the dephosphorization effect of slag; and (3) improving the metal yield, saving the energy consumption and effectively decreasing the production cost because the burn-in tailings as waste per se have low self cost but high iron content (more than 50 percent of TFe) and directly enter metal liquid through a steelmaking chemical reaction after melting.

Description

technical field [0001] The invention relates to a half-steel steelmaking technology, in particular to a method of using machine-burned tailings to assist half-steel steelmaking and slag production, and belongs to the technical field of metallurgy and steelmaking. Background technique [0002] Iron and steel enterprises using vanadium iron ore as raw materials, the molten iron used for steelmaking contains trace elements such as vanadium and titanium (abbreviated as vanadium-containing molten iron). In order to extract the vanadium element in vanadium-containing molten iron, a double-link process is adopted, that is, the molten iron first passes through After the vanadium is extracted, it is smelted into semi-steel, and then the semi-steel is used for steelmaking. Since most elements such as Si, Ti, Mn have been oxidized into the vanadium slag during the process of vanadium extraction, compared with ordinary molten iron, the content of Si, Ti, Mn and other elements in semi-st...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C5/36
CPCY02P10/20
Inventor 杜建良韩春良翁玉娟高海王金星杨昆
Owner HEBEI IRON AND STEEL