Composite foaming agent and preparation method and application thereof

A technology of compound foaming agent and auxiliary foaming agent, which is applied in the field of foaming agent and its preparation, can solve the problems of high decomposition temperature of azodicarbonamide, widening of plasticizing temperature range, excessive plasticizing of plastics, etc., and achieves Effects of reduced vulcanization time, reduced content, and low decomposition temperature

Active Publication Date: 2011-06-15
常州市英特玛柯橡塑科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the commonly used foaming agent is mainly azodicarbonamide plus zinc oxide, or azodicarbonamide plus zinc stearate. The vulcanization time of this foaming agent is about 15 minutes, and the temperature is 175 ° C ~ 185 ° C. It is yellow, and because the melting point of azodicarbonamide is too high, the plastic will be over-plasticized if it continues to heat, and the plasticizing temperature range of the material will be widened due to the addition of recycled materials, plus azodicarbonamide as a foaming agent The decomposition temperature of diformamide is too high, and the decomposition temperature range is too short to achieve the blending of the two
[0004] In addition, there are various kinds of recycled plastics, including shampoo bottles, shower gel bottles, soda bottles, etc. Due to the different tastes, the smell is stronger when they are mixed together, and the resulting products have an unpleasant smell, which is a major drawback of this industry.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] (Example 1, composite blowing agent and preparation method thereof)

[0019] The composite foaming agent of this embodiment is composed of 1.2 kg of azodicarbonamide, 300 g of sodium bicarbonate and 200 g of a foaming aid to form a powdery solid with a particle size of 1000 mesh to 1500 mesh.

[0020] The foaming aid is mixed evenly by 200g of attapulgite, 80g of zeolite, and 70g of calcite, then soaked in 300g of dilute hydrochloric acid with a concentration of 2wt%, then dried after stirring, and crushed with 80g of white carbon It is made by stirring the black mixture evenly.

[0021] The preparation method of the composite blowing agent of the present embodiment has the following steps:

[0022] ① Preparation of auxiliary foaming agent: mix 200g of attapulgite, 80g of zeolite, and 70g of calcite and stir evenly to obtain a mixed material; add 300g of dilute hydrochloric acid with a concentration of 2wt% to the mixed material and soak for 36 hours to make the mixtur...

Embodiment 2

[0026] (Example 2, composite blowing agent and preparation method thereof)

[0027] The rest of the composite blowing agent of the present embodiment is the same as in Example 1, except that the composition of the blowing aid is as follows: attapulgite is 200g, zeolite is 60g, calcite is 80g, and white carbon black is 60g , Concentration is 300g of dilute hydrochloric acid of 2wt%.

[0028] The rest of the preparation method of the above-mentioned composite blowing agent is the same as in Example 1, except that: when preparing the blowing aid in the step 1., the used raw material attapulgite is 200g, zeolite is 60g, calcite is 80g, white Carbon black is 60g, concentration is 2wt% dilute hydrochloric acid is 300g.

Embodiment 3

[0029] (Example 3, composite blowing agent and preparation method thereof)

[0030] The rest of the composite blowing agent of the present embodiment is the same as Example 1, except that: azodicarbonamide is 1.21kg, sodium bicarbonate is 300g, and foaming aid is 200g. The composition of the foaming aid is as follows: 200 g of attapulgite, 60 g of zeolite, 80 g of calcite, 60 g of white carbon black, and 300 g of dilute hydrochloric acid with a concentration of 2 wt%.

[0031] The rest of the preparation method of the above-mentioned composite foaming agent is the same as in Example 1, except that: when preparing the blowing aid in the step 1., the raw materials used are 200g of attapulgite, 60g of zeolite, 80g of calcite, and 80g of calcite. Carbon black is 60g, concentration is 2wt% dilute hydrochloric acid is 300g. When preparing the composite foaming agent in step ②, the azodicarbonamide used was 1.21kg, sodium bicarbonate was 300g, and the blowing aid was 200g.

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Abstract

The invention discloses a composite foaming agent, a preparation method thereof and application thereof. The composite foaming agent comprises azodicarbonamide, sodium bicarbonate and an auxiliary foaming agent in a weight ratio of (0.3-0.9):(0.2-0.6):(0.1-0.8). The auxiliary foaming agent is prepared by uniformly stirring attapulgite, zeolite and calcite, soaking the mixture in diluted hydrochloric acid of which the concentration is 0.5 to 6 weight percent, drying the mixture, crushing the dried mixture into powder, blending the powder and powdery white carbon black and uniformly stirring the mixture, wherein the weight ratio of the attapulgite to the zeolite to the calcite to the white carbon black is (0.3-0.8):(0.02-0.6):(0.1-0.8):(0.01-0.8). The composite foaming agent disclosed by the invention has relatively high liquidity and dispersibility, a low decomposition temperature and a long decomposition temperature period.

Description

technical field [0001] The invention relates to a foaming agent and its preparation method and application. Background technique [0002] Petroleum energy is becoming increasingly exhausted as a non-renewable energy source, but plastics are more and more widely used in life, and the regeneration of plastics has become an important part of energy saving, and the molecular weight of recycled plastics is gradually reduced due to one or more repeated uses , the processing temperature is very different from that of new materials, and the original plastic product processing technology and original formula must be changed accordingly. As the most widely used plastic polyethylene PE among the five general-purpose plastics, it has a wide range of applications, such as packaging materials, films, industrial insulation materials, cushioning materials, shoe materials, luggage and other items, and among these items, many of them use foam sponge products. Form (abbreviated as foam produc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/10C08J9/08C08L23/06C08L23/08
Inventor 杨晓梅肖春阳
Owner 常州市英特玛柯橡塑科技有限公司
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