Organic photoelectric material containing nitrogen thiophene, manufacturing method and application thereof
A technology of organic photoelectric materials and manufacturing methods, applied in the fields of luminescent materials, organic chemistry, photovoltaic power generation, etc., can solve the problems of low photoelectric conversion efficiency
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Embodiment 1
[0062] The nitrogen-containing thiophene organic photoelectric material of the present embodiment 1 uses R 1 , R 2 for hexyl, R 3 Take 3-ethyl-heptyl as an example, its structural formula is as follows:
[0063]
[0064] It can be seen from the structural formula that the nitrogen-containing thiophene organic photoelectric material in Example 1 has a symmetrical structure, with a hexathiophene ring and two pairs of cyano groups, and the cyano groups serve as electron-withdrawing groups. Through this uniform and symmetrical structure, nitrogen-containing Thiophene organic optoelectronic materials have relatively good light absorption properties and optoelectronic properties.
[0065] The preparation method of this hexathiophene adopts the concrete operations of the first scheme as follows:
[0066] 1) Preparation of 2-((2-bromo-5-(5-hexylthiophen-2-yl)thiophen-3-yl)methylene)malononitrile, whose structural formula is as follows:
[0067]
[0068] Since the nitrogen-co...
Embodiment 2
[0075] The nitrogen-containing thiophene organic photoelectric material in Example 2 takes the same final product of hexathiophene as in Example 1 as an example, and the preparation method of the hexathiophene is specifically operated as follows according to the second scheme.
[0076] 1) Preparation of 2-(2-(3-formyl-5-(5-hexylthiophen-2-yl)thiophen-2-yl)-N-[1-(2'-ethylhexyl)-3-ethane ylheptyl]-dithiophene[3,2-b:2',3'-d]pyrrol-5-yl)-5-(5-hexylthiophen-2-yl)thiophene-3-carbaldehyde, whose structural formula is as follows Shown:
[0077]
[0078] Similarly, the nitrogen-containing thiophene organic photoelectric material in Example 2 has a symmetrical structure, therefore, the compounds A and B in this step have the same structure, and only one kind of raw material needs to be provided to directly perform step 1), thus also The preparation process is simplified and the cost is reduced, and the production rate is higher than when different compounds A and B are used. Concre...
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