Foaming agent composition used for high temperature and high salt oil reservoir
A technology of composition and foaming agent, which is applied in the field of foaming agent composition, can solve the problems of poor thermal stability of foaming agent and cannot meet the needs, and achieve the effect of improving salt resistance
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Embodiment 1
[0025] (1) Add 93g (0.5 mole) dodecyl alcohol and the calcium oxide catalyst of alcohol weight 1% in the reactor that condensing device, stirring device and gas disperser are housed, when heating to 135 ℃ while flowing nitrogen, add 8g water , and stirred for 1 hour. Then first distilled water at normal pressure, then decompressed under 20 mm Hg vacuum, evaporated moisture at 140 DEG C in vacuum for 20 minutes, cooled the solution to 80 DEG C, slowly added dropwise neutralizing catalyst theoretical acid amount of 20% by weight concentrated sulfuric acid. Heat the system temperature to 80-90°C, turn on the vacuum system, dehydrate under high vacuum for 1 hour, then use nitrogen to blow 3-4 times to remove the air in the system, then adjust the reaction temperature of the system to 150°C Enter 155 grams of oxirane, control pressure<0.60MPa to carry out alkoxylation reaction; Obtain lauryl alcohol polyoxyethylene (7) ether.
[0026] (2) 240g (0.5 mole) of polyoxyethylene laury...
Embodiment 2
[0034] Take the foaming agent composition in [Example 1] and put it into a pressure bomb, put it into an oven and age it at 200°C for 10 days and take it out. Under the condition of a water bath at 90°C, the Roche method measures the foaming ability and foaming capacity of the composition after aging. The results of the half-life measured by the scanner are shown in Table 3.
[0035] table 3
[0036] X(weight)%
Embodiment 3
[0038]Get the foam composition lauryl alcohol polyoxyethylene (7) ether sodium benzene sulfonate 0.5 (weight)% in [embodiment 1], sodium dodecylbenzene sulfonate 0.1 (weight)%, carry out plugging performance In the evaluation experiment, the core tube filled with quartz sand has a permeability of 4D. The aqueous solution of the foaming agent composition is injected into the sand tube at a rate of 2mL / min, and nitrogen gas is injected at a rate of 9mL / min at the same time. The calculated resistance factor is 25.5. The foam flooding field requires a resistance factor greater than 4.
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