Method for preparing polyester fibers with ultraviolet-resistant and anti-pilling composite function

Abstract

The invention relates to a method for preparing polyester fibers with ultraviolet-resistant and anti-pilling composite function. The method comprises an esterification reaction procedure, a polymerization reaction procedure and a spinning procedure, wherein the esterification reaction procedure comprises a primary esterification reaction stage and a secondary esterification reaction stage, and aliphatic dicarboxylic acid or non-p-aryl dicarboxylic acid serving as a third monomer is introduced in the primary esterification reaction stage; flexible polyethylene glycol serving as a fourth monomer is introduced in the secondary esterification reaction stage; a hindered amine light stabilizer and a hindered phenol antioxidant which are respectively prepared by using acetic acid and ethylene glycol as solvents and hydroxy silicone oil are added after the esterification is completed; and after the pre-polymerization of the polymerization reaction procedure is completed and before final polymerization, an ultraviolet absorbent is added. Before the spinning procedure, polyester slices are pre-crystallized and dried. The polyester fibers obtained by the method have excellent ultraviolet-resistant and anti-pilling function; and after the polyester fibers are woven into knitted fabrics and woven fabrics, tests show the related technical indexes that: the ultraviolet transmission rate is less than or equal to 5.0 percent, and the anti-pilling performance is more than or equal to level 4.

Description

technical field [0001] The invention relates to a preparation method of polyester fiber with anti-ultraviolet and anti-pilling composite functions. Background technique [0002] Since the advent of polyester fiber, it has been widely used in clothing textiles due to its good strength, excellent wrinkle resistance, drape performance and washable wearability. After decades of rapid development, PET polyester fiber has become the world's most It is the synthetic polyester variety with the largest output and widest application range. However, compared with various natural fibers, there are still many shortcomings: hard hand feeling, poor hygroscopicity, poor UV resistance, easy to generate static electricity, easy to pilling, difficult to dye, etc. Although natural fibers such as cotton, silk, wool, hemp, etc. have good dyeing performance, the fabric has air permeability, good sweat absorption and moisturizing performance, no static electricity, and good comfort, but they are e...

AI Technical Summary

Problems solved by technology

However, compared with various natural fibers, there are still many shortcomings: hard hand feeling, poor hygroscopicity, poor UV resistance, easy to generate static electricity, easy to pilling, difficult to dye, etc.

The disadvantage of this method is: benzotriazole is an organic phenolic compound, which exists as a protonic acid under high temperature conditions, which can destroy the inorganic nano-powder TiO 2 and Al 2 o 3 or SiO 2 Surface organic treatment agent, leading to the agglomeration of inorganic nanopowders in the pre-aggregation process

[0008] In summary, the existing technologies mainly rely on the huge specific surface area of ​​inorganic nano-powders to diffusely scatter ultraviolet rays to produce an anti-ultraviolet effect, and the stability and efficiency of the anti-ultraviolet effect need to be improved. Starting from the mechanism, the preparation of polyester with better anti-ultraviolet effect and good spinnability

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