Method for preparing gasoline from methanol
A technology for methanol and gasoline, which is applied in the fields of refined hydrocarbon oil, petroleum industry, reformed naphtha, etc., can solve the problems of difficulty in making gasoline, low content of methanol, and incapacity of light petroleum fractions, and achieves good technical effects. Effect
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Embodiment 1
[0028] The composition is 0.25%Pd / 60%ZSM-5 / 40%Al 2 o 3 Under the action of a solid acid catalyst, light naphtha with a dry point of 190°C and methanol with a water content of 20% are used as raw materials for the reaction. The reaction conditions and results are shown in Table 1:
[0029] Table 1 methanol and light naphtha reaction results under the action of molecular sieve catalyst
[0030] Raw material composition
0.7A / 0.3B
0.8A / 0.2B
0.9A / 0.1B
Raw bromine value, g / 100g
13.1
14.9
16.8
Reaction temperature, °C
400
350
300
Weight airspeed, h -1
10.0
5.0
2.0
System pressure, MPa
5.0
3.5
2.0
Liquid yield, wt%
97.5
99.1
99.3
Gasoline yield, wt%
78.3
86.4
92.5
Diesel yield, wt%
2.3
1.5
1.2
Research Gasoline Octane Number
92
94
92
Oxygenated compounds, ppm...
Embodiment 2
[0034] Under the action of alumina solid acid catalyst loaded with 5% phosphotungstic acid, heavy naphtha with a dry point of 205°C and anhydrous methanol were used as raw materials for the reaction. The reaction conditions and results are shown in Table 2:
[0035] Table 2 Reaction results of methanol and heavy naphtha under the action of alumina as the main catalyst
[0036] Raw material composition
[0037] Note: A stands for heavy naphtha, B stands for methanol.
Embodiment 3
[0039] The composition is 0.15%Pt / 60%USY / 40%SiO 2 Under the action of a solid acid catalyst, the catalytic cracking naphtha with a dry point of 205°C and methanol with a water content of 60% are used as raw materials for the reaction. The reaction conditions and results are shown in Table 3:
[0040] Table 3 Reaction results of methanol and FCC naphtha under the action of molecular sieve catalyst
[0041] Raw material composition
[0042] Note: A represents catalytic cracking naphtha, B represents methanol.
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