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Method for preparing gasoline from methanol

A technology for methanol and gasoline, which is applied in the fields of refined hydrocarbon oil, petroleum industry, reformed naphtha, etc., can solve the problems of difficulty in making gasoline, low content of methanol, and incapacity of light petroleum fractions, and achieves good technical effects. Effect

Active Publication Date: 2015-04-08
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] The technical problem to be solved by the present invention is that the light petroleum distillate existing in the prior art cannot or is difficult to be made into gasoline and in the process of making gasoline, the mixing amount of methanol is relatively low under the condition of not remodeling the engine, which is easy to corrode equipment and carbon deposits. To solve the problem, provide a new gasoline production method, which has light petroleum fractions that can be better utilized, without the need to modify the existing engine, the proportion of methanol in the production raw materials is high, and there is no need to add surface Activator, high calorific value of gasoline products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The composition is 0.25%Pd / 60%ZSM-5 / 40%Al 2 o 3 Under the action of a solid acid catalyst, light naphtha with a dry point of 190°C and methanol with a water content of 20% are used as raw materials for the reaction. The reaction conditions and results are shown in Table 1:

[0029] Table 1 methanol and light naphtha reaction results under the action of molecular sieve catalyst

[0030] Raw material composition

0.7A / 0.3B

0.8A / 0.2B

0.9A / 0.1B

Raw bromine value, g / 100g

13.1

14.9

16.8

Reaction temperature, °C

400

350

300

Weight airspeed, h -1

10.0

5.0

2.0

System pressure, MPa

5.0

3.5

2.0

Liquid yield, wt%

97.5

99.1

99.3

Gasoline yield, wt%

78.3

86.4

92.5

Diesel yield, wt%

2.3

1.5

1.2

Research Gasoline Octane Number

92

94

92

Oxygenated compounds, ppm...

Embodiment 2

[0034] Under the action of alumina solid acid catalyst loaded with 5% phosphotungstic acid, heavy naphtha with a dry point of 205°C and anhydrous methanol were used as raw materials for the reaction. The reaction conditions and results are shown in Table 2:

[0035] Table 2 Reaction results of methanol and heavy naphtha under the action of alumina as the main catalyst

[0036] Raw material composition

[0037] Note: A stands for heavy naphtha, B stands for methanol.

Embodiment 3

[0039] The composition is 0.15%Pt / 60%USY / 40%SiO 2 Under the action of a solid acid catalyst, the catalytic cracking naphtha with a dry point of 205°C and methanol with a water content of 60% are used as raw materials for the reaction. The reaction conditions and results are shown in Table 3:

[0040] Table 3 Reaction results of methanol and FCC naphtha under the action of molecular sieve catalyst

[0041] Raw material composition

[0042] Note: A represents catalytic cracking naphtha, B represents methanol.

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PUM

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Abstract

The invention relates to a method for preparing gasoline from methanol and light petroleum distillates, and aims to mainly solve the problems that light petroleum distillates are unable or hard to be used to prepare gasoline, and during gasoline preparation process, without transforming an engine, methanol has a low incorporation amount and is easy to corrode equipment as well as result carbon deposition in the prior art. The method of the invention adopts a technical scheme consisting of: taking methanol or dimethyl ether and light petroleum distillates as the raw materials, and under the conditions of a reaction temperature of 300-500DEG C, a reaction pressure ranging from normal pressure to 10.0MPa, and a raw material weight hourly space velocity of 0.3-10h<-1>, contacting the raw materials with a solid acid catalyst, and making the methanol and the light petroleum distillates undergo an alkylation reaction on the catalyst so as to obtain a gasoline product with the weight concentration of oxygen-containing compounds less than 100ppm. The technical scheme of the invention well solves the problem, and can be used in the industrial production of gasoline.

Description

technical field [0001] The invention relates to a method for preparing gasoline from methanol and light petroleum fractions. Background technique [0002] Gasoline is a large category of oil products. It is composed of complex hydrocarbons with about 5 to 12 carbon atoms. It is flammable and is mainly used as fuel for vehicle engines. In the prior art, gasoline is generally produced by petroleum fractionation or heavy fraction cracking. Due to limited oil resources and declining reserves, many oil fields have entered the late stage of exploitation, and the cost of exploitation has risen, resulting in tight supply of gasoline and high prices. [0003] In the process of petroleum refining, a large number of light petroleum fractions with carbon atoms of 1 to 12 will be produced. A small amount of these light petroleum fractions are obtained directly from petroleum distillation, and most of them are the products of cracking reactions. Among these light petroleum fractions, C1...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G35/06C10G35/095C10G29/22C10G3/00C10G50/00
CPCY02P30/20
Inventor 孔德金王雨勃郭宏利侯敏杨德琴
Owner CHINA PETROLEUM & CHEM CORP
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