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Heavy oil conversion method

A heavy oil cracking and heavy oil technology, applied in the field of heavy oil conversion, can solve the problems of decreased coke transfer agent activity, increased dry gas and coke content, poor selectivity, etc., to suppress metal deactivation and coking deactivation, and reduce dry gas and coke content, the effect of reducing the amount of treatment

Active Publication Date: 2014-12-31
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In the disclosed method of CN1253368C, when petroleum hydrocarbon is contacted with coke transfer agent, need to use a large amount of water to generate water vapor, to fluidize coke transfer agent, but when using water vapor as fluidization medium, petroleum hydrocarbon and After the contact product of the coke contact agent is treated, the water vapor is converted into liquid water and separated from the reaction product. The water thus produced contains a large amount of pollutants and needs to be purified before it can enter the steam generating device again and be converted into water vapor, thus higher energy consumption
[0009] Moreover, when the carbon residue and metal content of the petroleum hydrocarbons are high, a large amount of carbonaceous substances and metals in the petroleum hydrocarbons are deposited on the coke transfer agent, resulting in a decrease in the activity of the coke transfer agent and poor selectivity. This in turn increases the content of dry gas and coke in the product
Although feeding hydrogen (e.g., from the synthesis gas generated in the regenerator) to the reactor can mitigate the coking and metal deactivation of the coke transfer agent to some extent, the resulting product is liquid The content of components still needs to be further improved

Method used

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Examples

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Effect test

Embodiment 1

[0058] This example is used to illustrate the heavy oil conversion method according to the present invention.

[0059] according to figure 1 In the process flow shown, the heavy oil A preheated to 300°C is sent into the fluidized bed reactor by using steam and light hydrocarbon as the fluidized medium, and is contacted with the coke transfer agent under the condition of heavy oil cracking, wherein:

[0060] The mass ratio of the light hydrocarbons and the water vapor to the heavy oil is 0.10:0.05:1, and in the light hydrocarbons, C 1 and C 2 The content of the component is 75% by mass, C 3 The content of the above components is 8% by mass;

[0061] The coke transfer agent is silica-alumina microspheres produced by spray drying technology, the average particle diameter of the coke transfer agent is 70 μm, the average pore diameter is 30 nm, and the micro-reaction activity is 30; wherein, the preparation method of the coke transfer agent is: Pseudo-boehmite and kaolin were m...

Embodiment 2

[0077] This example is used to illustrate the heavy oil conversion method according to the present invention.

[0078] Adopt the method identical with embodiment 1 to carry out the conversion of heavy oil, difference is:

[0079] The heavy oil B used as raw material, and the mass ratio of the light hydrocarbon and the water vapor to the heavy oil is 0.05:0.10:1, in the light hydrocarbon, C 1 and C 2 The content of the component is 80% by mass, C 3 The content of the above components was 3% by mass.

[0080] The coke transfer agent is produced by spray drying technology, the average particle diameter of the coke transfer agent is 78 μm, the average pore diameter is 98nm, and the micro-reaction activity is 20; the preparation method of the coke transfer agent is the same as that of Example 1, The difference is that clay, pseudo-boehmite and alumina sol are mixed in water for pulping, based on the total amount of clay, pseudo-boehmite and alumina sol, the amount of clay is 50%...

Embodiment 3

[0085] This example is used to illustrate the heavy oil conversion method according to the present invention.

[0086] Adopt the method identical with embodiment 1 to carry out the conversion of heavy oil, difference is:

[0087] The heavy oil C used as raw material, and the mass ratio of the light hydrocarbon and the water vapor to the heavy oil is 0.13:0:1, in the light hydrocarbon, C 1 and C 2 The content of the component is 60% by mass, C 3 The content of the above components was 10% by mass.

[0088] The coke transfer agent is silica-alumina microspheres produced by spray drying technology. The coke transfer agent has an average particle diameter of 68 μm, an average pore diameter of 50 nm, and a microreactive activity of 30; the preparation method of the coke transfer agent is the same as in Example 1. The method is the same, but the difference is that based on the total amount of pseudo-boehmite and kaolin, the amount of pseudo-boehmite is 15% by mass, and the amount...

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Abstract

The invention provides a heavy oil conversion method which comprises the following steps: under a heavy oil cracking condition, contacting heavy oil with a coke transfer agent in a reactor; performing oil-agent separation of the contact product to obtain an oil gas component and a coke transfer agent to be regenerated, wherein the method also separates light hydrocarbons in the oil gas component, and at least part of the light hydrocarbons are delivered into the reactor. The method of the invention, on one hand, has the effect of fluidization of the coke transfer agent, and on the other hand, can effectively inhibit metal inactivation and coking inactivation of the coke transfer agent, reduces the contents of dry gas and coke in the product, and improve the content of liquid components. The method of the invention can also significantly reduce treatment amounts of subsequent sewage treatment devices and water vapor generation devices, and realize the effect of energy consumption reduction.

Description

technical field [0001] The invention relates to a heavy oil conversion method. Background technique [0002] With the development of the world economy, the demand for light, clean fuel oil is also growing rapidly. However, the crude oil is becoming heavier and inferior all over the world (mainly manifested as high density, high viscosity, high carbon residue, high heavy metal content and high sulfur and nitrogen content of crude oil, etc.). These factors have presented many new challenges to the refining industry. [0003] At present, in terms of mechanism, heavy oil processing is mainly divided into two categories: decarburization and hydrogenation. [0004] Hydrogenation mainly includes hydrofining and hydrocracking. The hydrogenation process is of great significance for increasing the processing depth of crude oil, improving the quality of products, and increasing the yield of light oil products; however, the heavy oil hydrogenation process not only has high operating ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G55/06
Inventor 李延军张书红王子军汪燮卿张美菊于凯
Owner CHINA PETROLEUM & CHEM CORP