Heavy oil conversion method
A heavy oil cracking and heavy oil technology, applied in the field of heavy oil conversion, can solve the problems of decreased coke transfer agent activity, increased dry gas and coke content, poor selectivity, etc., to suppress metal deactivation and coking deactivation, and reduce dry gas and coke content, the effect of reducing the amount of treatment
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Embodiment 1
[0058] This example is used to illustrate the heavy oil conversion method according to the present invention.
[0059] according to figure 1 In the process flow shown, the heavy oil A preheated to 300°C is sent into the fluidized bed reactor by using steam and light hydrocarbon as the fluidized medium, and is contacted with the coke transfer agent under the condition of heavy oil cracking, wherein:
[0060] The mass ratio of the light hydrocarbons and the water vapor to the heavy oil is 0.10:0.05:1, and in the light hydrocarbons, C 1 and C 2 The content of the component is 75% by mass, C 3 The content of the above components is 8% by mass;
[0061] The coke transfer agent is silica-alumina microspheres produced by spray drying technology, the average particle diameter of the coke transfer agent is 70 μm, the average pore diameter is 30 nm, and the micro-reaction activity is 30; wherein, the preparation method of the coke transfer agent is: Pseudo-boehmite and kaolin were m...
Embodiment 2
[0077] This example is used to illustrate the heavy oil conversion method according to the present invention.
[0078] Adopt the method identical with embodiment 1 to carry out the conversion of heavy oil, difference is:
[0079] The heavy oil B used as raw material, and the mass ratio of the light hydrocarbon and the water vapor to the heavy oil is 0.05:0.10:1, in the light hydrocarbon, C 1 and C 2 The content of the component is 80% by mass, C 3 The content of the above components was 3% by mass.
[0080] The coke transfer agent is produced by spray drying technology, the average particle diameter of the coke transfer agent is 78 μm, the average pore diameter is 98nm, and the micro-reaction activity is 20; the preparation method of the coke transfer agent is the same as that of Example 1, The difference is that clay, pseudo-boehmite and alumina sol are mixed in water for pulping, based on the total amount of clay, pseudo-boehmite and alumina sol, the amount of clay is 50%...
Embodiment 3
[0085] This example is used to illustrate the heavy oil conversion method according to the present invention.
[0086] Adopt the method identical with embodiment 1 to carry out the conversion of heavy oil, difference is:
[0087] The heavy oil C used as raw material, and the mass ratio of the light hydrocarbon and the water vapor to the heavy oil is 0.13:0:1, in the light hydrocarbon, C 1 and C 2 The content of the component is 60% by mass, C 3 The content of the above components was 10% by mass.
[0088] The coke transfer agent is silica-alumina microspheres produced by spray drying technology. The coke transfer agent has an average particle diameter of 68 μm, an average pore diameter of 50 nm, and a microreactive activity of 30; the preparation method of the coke transfer agent is the same as in Example 1. The method is the same, but the difference is that based on the total amount of pseudo-boehmite and kaolin, the amount of pseudo-boehmite is 15% by mass, and the amount...
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Abstract
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