Coupling agent modified calcium carbonate filled polypropylene plastic and preparation method thereof

A polypropylene plastic and calcium carbonate technology, applied in the field of plastic materials and its preparation, can solve problems such as uneven mixing of materials, affecting product performance, and reduction of effective cross-sectional area

Active Publication Date: 2013-04-10
河北立信化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Adding inorganic fillers such as calcium carbonate to plastics can improve the heat resistance, wear resistance, dimensional stability and rigidity of the product, and reduce the cost of the product, but the powder is added to the polymer material without treatment, and the filler and There is an obvious interface between the polymers, just like there are many cavities in the matrix resin, the effectiv

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Each raw material was weighed according to the data corresponding to Example 1 in Table 1.

[0028] (1) Dilute the coupling agent with xylene, a solvent that is 5 times the weight of the coupling agent, and then disperse it evenly in calcium carbonate, completely volatilize the xylene through an oven, and then grind the dried calcium carbonate into fine particles with a pulverizer. powder to produce modified calcium carbonate.

[0029] (2) Add polypropylene and modified calcium carbonate into the mixer and stir, control the speed at 300-400r / min, stirring temperature at 70-80°C, stirring time for 2-4 minutes, and then extrude and granulate through the screw extruder , the extrusion temperature is 180-200° C., cooling and molding in cold water of 10-40° C., and the coupling agent modified calcium carbonate filled polypropylene plastic is obtained.

[0030] Obviously, the preparation of modified calcium carbonate is a common method in this industry, and similar effects c...

Embodiment 2

[0034] Each raw material was weighed according to the data corresponding to Example 2 in Table 1. The method described in Example 1 was used to prepare the coupling agent modified calcium carbonate filled polypropylene plastic.

Embodiment 3

[0036] Each raw material was weighed according to the data corresponding to Example 3 in Table 1. The method described in Example 1 was used to prepare the coupling agent modified calcium carbonate filled polypropylene plastic.

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PUM

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Abstract

The invention discloses a coupling agent modified calcium carbonate filled polypropylene plastic and a preparation method thereof. The coupling agent modified calcium carbonate filled polypropylene plastic comprises the following components in parts by weight: 100 parts of polypropylene, 10-20 parts of calcium carbonate, and 0.1-0.3 part of coupling agent, wherein the coupling agent preferably consists of 10-30 parts of gamma-chloropropyltriethoxysilane, 50-70 parts of isopropyl tri(dioctylphosphate)titanate and 10-30 parts of Polyethyleneglycol trimethoxysilylpropyl ether. According to the invention, calcium carbonate is modified by adding the coupling agent so that the surface of calcium carbonate changes from hydrophilicity into lipophilicity and then can be tightly combined with polypropylene, and the performances of a plastic material are improved; furthermore, the coupling agent is preferable so that the viscosity is reduced, and each mechanical property is better; and the coupling agent modified calcium carbonate filled polypropylene plastic has the advantages of good tensile strength, elongation at break, notch impact strength, thermal deformation temperature and Rockwell hardness.

Description

technical field [0001] The invention relates to a plastic material and a preparation method thereof, in particular to a coupling agent modified calcium carbonate filled polypropylene plastic and a preparation method thereof. Background technique [0002] Polypropylene, abbreviated as PP, CAS number: 9003-07-0. It is a thermoplastic resin obtained by polymerizing propylene. It was first put into industrial production in Italy in 1957, and it is another important plastic variety after polyethylene (PE). It has good heat resistance, and it will not be destroyed when it is cooked at 135°C for 1000 hours. The specific heat capacity and thermal conductivity of PP are smaller than that of PE, but its thermal insulation is better than that of PE. PP is a non-polar polymer with excellent dielectric and electrical insulation properties. The electrical properties are basically not affected by ambient humidity and electric field frequency. Within the allowable operating range, the inc...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K9/06C08K9/04C08K3/26B29C47/92B29C48/92
Inventor 宋国新黄毅
Owner 河北立信化工有限公司
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