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Low refractive index diffuser element having interconnected voids

A low-refractive index layer, diffuser technology, used in diffuser elements, optical elements, instruments, etc., to solve problems such as limited size range and uniformity, and limitations of available material types

Inactive Publication Date: 2013-06-12
3M INNOVATIVE PROPERTIES CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Washing steps can limit the size range and uniformity of the resulting pores or voids
These techniques are also limited by the type of materials available

Method used

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  • Low refractive index diffuser element having interconnected voids
  • Low refractive index diffuser element having interconnected voids
  • Low refractive index diffuser element having interconnected voids

Examples

Experimental program
Comparison scheme
Effect test

example

[0061] Comparative example CE-1 is made of polyvinyl alcohol Kuraray PVA-235 and fumed silica dispersion Cab-O-Sperse TM 1020K mixture preparation. PVA was 88% hydrolyzed medium molecular weight polyvinyl alcohol available from Kuraray USA, Houston, TX. Cab-O-Sperse TM 1020K is a non-surface modified basic stable dispersion of L90 fumed silica available from Cabot Corporation, Billerica, MA. In a typical process, 138.8g of 7.2wt% PVA235 aqueous solution was charged into an 800ml plastic beaker (10.0g PVA235 by dry weight), and then 2.0g of 10wt% Tergitol was added TM Min-Foam1X and 1ml concentrated NH 4 OH solution. Tergitol TM Min-Foam 1X is a nonionic surfactant available from Dow Chemical of Midland, MI. Mix the ingredients thoroughly using a stir bar, then add 200g of Cab-O-Sperse TM 1020K, water with 20 wt% fumed silica and an additional 162g deionized (DI) water. The components were thoroughly mixed under low shear using an air mixer to reduce foaming. After mix...

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Abstract

An optical diffuser layer includes a binder, a plurality of metal oxide particles dispersed in the binder, and a plurality of interconnected voids. A plurality of haze generating particles are dispersed in the binder. The optical diffuser layer has an effective refractive index of 1.3 or less.

Description

Background technique [0001] Articles with nanoscale pore or void structures are useful in a variety of applications based on the optical, physical or mechanical properties provided by their nanovoided compositions. For example, a nanovoided article comprises a polymeric solid network or matrix at least partially surrounding pores or voids. The pores or voids are usually filled with a gas such as air. The size of the pores or voids in a nanovoided article can generally be described as having an average effective diameter that can range from about 1 nanometer to about 1000 nanometers. The International Union of Pure and Applied Chemistry (IUPAC) has defined three size categories of nanoporous materials: micropores with voids smaller than 2 nm, mesopores with voids between 2 nm and 50 nm, and voids larger than 50nm macropores. Each of the above different sizes can provide unique properties to the nanovoided article. [0002] Several techniques have been used to create porous ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B1/11G02B5/02
CPCG02B1/11G02B5/0242G02B2207/107
Inventor 威廉·D·科焦迈克尔·L·斯坦纳刘涛刘兰虹
Owner 3M INNOVATIVE PROPERTIES CO