Adsorbent for selectively reducing release amount of volatile carbonyl and phenol compounds in cigarette smoke and preparation method and application of adsorbent

A technology for phenolic compounds and cigarette smoke, applied in chemical instruments and methods, applications, tobacco, etc., can solve the problem of many processes for preparing complex materials, reducing the release of various volatile carbonyl compounds and phenolic substances, and complex processes. and other problems, to achieve the effect of high safety, simple preparation process and simple process

Active Publication Date: 2013-10-09
CHINA TOBACCO JIANGSU INDAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent 201010542254.8 utilizes the characteristic that CN- has a strong complexation with metal ions, and different metal ions are complexed on a porous carrier with a large specific surface area to obtain a class of metal complex materials that can be used to selectively reduce cigarette smoke. The amount of HCN released in the air, but the preparation of complex materials has many processes and complicated procedures, and it is necessary to load three or more metal ions on the carrier
Using a metal ion adsorbent, it can selectively and greatly reduce various volatile carbonyl compounds and The release of phenolic substances, but also has a simple preparation process, can be mass-produced, and has application prospects. There are no relevant patents and literature reports in the field of cigarette harm reduction and tar reduction.

Method used

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  • Adsorbent for selectively reducing release amount of volatile carbonyl and phenol compounds in cigarette smoke and preparation method and application of adsorbent
  • Adsorbent for selectively reducing release amount of volatile carbonyl and phenol compounds in cigarette smoke and preparation method and application of adsorbent

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Experimental program
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Effect test

Embodiment 1

[0029] 1. Preparation of adsorbent

[0030]1) Prepare a CuCl solution with a mass fraction of 20% and a PdCl solution with a mass fraction of 10% 2 Solution, the two are mixed with a volume of 2:1 to obtain a mixed solution of the two;

[0031] 2) Use a sprayer to evenly spray the mixed solution prepared in step 1) on the surface of activated carbon fibers to obtain a composite material loaded with metal ions Cu and Pd, in which the loadings of Cu and Pd elements are 21.4% and 12.5% ​​of the mass of activated carbon fibers respectively ;

[0032] 3) Dry the composite material obtained in step 2) at 120° C. for 40 minutes to obtain the adsorbent of the present invention.

[0033] 2. Application of adsorbent

[0034] The prepared adsorbent material is made of a coaxial core binary composite filter tip using the existing molding method of cigarette filter rods and cellulose acetate filter rods. The trial production quantity is 8,000 cigarettes, and the adsorbent material conta...

Embodiment 2

[0042] 1. Preparation of adsorbent

[0043] Prepare CuCl with a mass fraction of 30% 2 solution, use a nebulizer to spray CuCl 2 The solution is evenly sprayed on the surface of the activated carbon fiber to obtain a composite material loaded with metal ion Cu, wherein the loading amount of the Cu element is 13.6% of the mass of the activated carbon fiber; then the composite material is dried at 120 ° C for 40 minutes to obtain the adsorbent of the present invention .

[0044] 2. Application of adsorbent

[0045] The prepared adsorbent material is made of a coaxial core binary composite filter tip using the existing molding method of a cigarette filter rod and a cellulose acetate filter rod. The trial production quantity is 8,000 cigarettes, and the adsorbent material contained in each cigarette is 15 mg.

[0046] All the other steps are the same as in Example 1, and the measurement results are shown in Table 1.

[0047] The results show that after the adsorbent is applied...

Embodiment 3

[0049] Preparation of NiCl with a mass fraction of 20% 2 The solution was evenly sprayed on the surface of the zeolite molecular sieve with a sprayer, and the Ni element loading was 30% of the mass of the zeolite molecular sieve, and then the composite material was dried at 150°C for 40 minutes. The prepared adsorbent material adopts the existing molding method of cigarette filter rods and cellulose acetate filter rods to make binary composite filter tips. The trial production quantity is 8,000 cigarettes, and the adsorbent material contained in each cigarette is 11 mg. All the other steps are the same as in Example 1, and the measurement results are shown in Table 1.

[0050] The results show that after the adsorbent is applied to cigarettes, it can significantly and selectively reduce the main phenolic compounds and volatile carbonyl compounds in the mainstream smoke, and the content of CO and hydrocyanic acid in the smoke is also reduced. The cigarettes prepared by adoptin...

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PUM

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Abstract

The invention discloses an adsorbent for selectively reducing the release amount of volatile carbonyl and phenol compounds in cigarette smoke and a preparation method and application of the adsorbent. The preparation method comprises the following steps of: preparing an aqueous solution of inorganic metal salt, directly spraying the aqueous solution on the surface of any one carrier material of activated carbon fibers, a zeolite molecular sieve, sepiolite, activated carbon and the like, performing drying treatment and preparing the adsorbent. When the adsorbent is applied to cigarettes in a binary composite filter stick form, the release amount of multiple volatile carbonyl compounds and phenol compounds in main stream smoke of the cigarettes can be greatly reduced while the sensory quality of the cigarettes is not obviously influenced. The adsorbent has the obvious effect of selectively reducing the cigarette harm, is extremely simple in preparation process, low in cost and safe, has the effect of environment protection, and has wide application prospects in the field of cigarette harm reduction, and the large-scale industrial production of the adsorbent is easily realized.

Description

technical field [0001] The invention relates to the technical field of reducing tar and harm of cigarettes and the preparation of cigarette filters, in particular to an adsorbent capable of selectively reducing the release of phenols and carbonyl compounds in mainstream smoke of cigarettes and its preparation method and application. Background technique [0002] Cigarettes undergo a series of chemical and physical changes such as pyrolysis, degradation, and distillation during the combustion process. The components of cigarette smoke formed are complex. More than 5,000 components have been identified, and volatile carbonyl and phenolic compounds are important among them. Harmful and carcinogenic ingredients. Studies have shown that volatile carbonyl compounds such as formaldehyde, acetaldehyde, and crotonaldehyde with less than five carbons can cause diseases through inhalation and skin absorption, especially crotonaldehyde is a highly toxic substance with cilia toxicity, an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/18B01J20/30A24D3/10
Inventor 庄亚东朱怀远刘献军曹毅张媛尤晓娟盛金沈晓晨秦艳华朱莹韩开冬熊晓敏张华
Owner CHINA TOBACCO JIANGSU INDAL
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