Method for preparing unsaturated fatty acid zinc salt reinforced natural rubber in in-situ reaction

A technology of fatty acid zinc salt and natural rubber, which is applied in the field of preparation of unsaturated fatty acid zinc salt reinforced natural rubber generated in situ, can solve problems such as poor rubber reinforcement effect, and achieves improved dispersion effect and improved chemical cross-linking. effect, strong binding effect
CN103554560AInactive Publication Date: 2014-02-05AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI +1

Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI
Publication Date
2014-02-05
Estimated Expiration
Not applicable · inactive patent
Patent Text Reader

Abstract

The invention relates to a method for preparing unsaturated fatty acid zinc salt reinforced natural rubber in in-situ reaction. The method comprises the following specific steps: adding nano-zinc oxide, a proper amount of coupling agent, an anionic surfactant and emulsion hydroxyethyl methylacrylate rubber, and preparing nano-zinc oxide emulsion dispersion by adopting stirring and ultrasonic dispersion; stabilizing emulsion natural rubber by adopting a proper amount of nonionic surfactant, uniformly mixing the nano-zinc oxide emulsion dispersion in the emulsion natural rubber, and dropwise adding an unsaturated fatty acid and an initiation cross-linking agent, thereby obtaining an in-situ reaction unsaturated fatty acid zinc salt-natural rubber composite material in a rubber latex state; further solidifying, pressing, washing, drying and performing other standard China rubber conventional processing technologies on the composite material, thereby obtaining an unsaturated fatty acid zinc salt-natural rubber composite material in a dry glue state. The composite material prepared by the method is good in performance.
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Description

technical field

[0001] The present invention relates to a kind of preparation method of in-situ generated unsaturated fatty acid zinc salt reinforced natural rubber, in particular to a method utilizing the excellent compatibility between hydroxyethyl methacrylate rubber and natural rubber and the compatibility of unsaturated fatty acid with natural rubber The invention relates to a method for preparing a reactive unsaturated fatty acid zinc salt reinforced natural rubber composite material through in-situ chemical reaction of nanometer zinc oxide, belonging to the technical field of rubber composite material production. Background technique

[0002] Natural rubber (NR) is a non-polar rubber, and it needs to be reinforced with fillers when it is used alone as a rubber material. At present, the reinforcing fillers widely used in the rubber industry mainly include carbon black, silica, fiber, clay, calcium carbonate, etc. For a long time, zinc oxide was only used as a vulcaniz...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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