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Solid active bromine bactericidal algicide

A bromine bactericide and algaecide technology, applied in H-69 new solid active bromine bactericide and algicide and its preparation field, can solve the problems of narrow range of effective bactericidal pH value, low bactericidal effect of hypochlorite, sterilizing Algae performance is poor and other problems, to achieve the effect of strong stripping, strong bactericidal performance, and small environmental impact

Inactive Publication Date: 2014-03-05
WUJIN HUADONG CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantages of chlorine-containing fungicides are also obvious. The effective sterilization pH value range of chlorine-containing fungicides is narrow. When the pH value of water is 7.5, more than 50% of hypochlorous acid will dissociate. Chloric acid dissociates, and the hypochlorite formed by dissociation has little bactericidal effect
[0003] However, bromine-containing bactericidal algicides, such as bromochlorohydantoin, have strong bactericidal ability, but they can only inhibit the growth of algae in terms of algae removal performance, and the algae removal performance is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The solid active bromine bactericidal and algaecide of this embodiment includes: 30% by mass of 2-bromo-4,5-dimethoxybenzenepropionitrile and 15% by weight of 3-bromo-1-chloro-5,5 Dimethylhydantoin, dibromonitrilopropionamide, 25% diquaternary ammonium salt activator, 10% dibromocyanoacetamide, 15% bronopol.

[0035] The preparation method of the above solid active bromine bactericidal and algaecide includes the following steps:

[0036] (1) Combine 2-bromo-4,5-dimethoxybenzenepropionitrile, bronopol, 3-bromo-1-chloro-5,5-dimethylhydantoin, dibromonitrilopropionamide and Dibromocyanoacetamide is continuously stirred and dispersed in the mixing mixer;

[0037] (2) Stirring is not stopped after stirring, and the double quaternary ammonium salt aqueous solution is added and stirred;

[0038] (3) After thoroughly mixing, dry the mixed solid at 70°C for 5 hours.

[0039] The solid active bromine bactericidal and algaecide is white powder or solid, has a light bromine smell and is ea...

Embodiment 2

[0045] The solid active bromine bactericidal and algaecide of this embodiment includes: 35% by mass of 2-bromo-4,5-dimethoxybenzenepropionitrile and 10% of 3-bromo-1-chloro-5,5 Dimethylhydantoin, 10% dibromonitrilopropionamide, 20% diquaternary ammonium salt activator, 15% dibromocyanoacetamide, 10% bronopol.

[0046] The preparation method of the above solid active bromine bactericidal and algaecide includes the following steps:

[0047] (1) Combine 2-bromo-4,5-dimethoxybenzenepropionitrile, bronopol, 3-bromo-1-chloro-5,5-dimethylhydantoin, dibromonitrilopropionamide and Dibromocyanoacetamide is continuously stirred and dispersed in the mixing stirrer, stirring for 75 minutes, and the stirring rate is 300r / min;

[0048] (2) Stirring is not stopped after stirring, and the double quaternary ammonium salt aqueous solution is added and stirred;

[0049] (3) After thoroughly mixing, dry the mixed solid.

[0050] The solid active bromine bactericidal and algaecide is white powder or solid,...

Embodiment 3

[0056] The solid active bromine bactericidal and algicide of this embodiment includes: 40% by mass of 2-bromo-4,5-dimethoxybenzenepropionitrile, and 5% of 3-bromo-1-chloro-5,5 Dimethylhydantoin, 5% dibromonitrilopropionamide, 15% diquaternary ammonium salt activator, 20% dibromocyanoacetamide, 15% bronopol.

[0057] The preparation method of the above solid active bromine bactericidal and algaecide includes the following steps:

[0058] (1) Combine 2-bromo-4,5-dimethoxybenzenepropionitrile, bronopol, 3-bromo-1-chloro-5,5-dimethylhydantoin, dibromonitrilopropionamide and Dibromocyanoacetamide is continuously stirred and dispersed in the mixing mixer;

[0059] (2) Stirring is not stopped after stirring, and the double quaternary ammonium salt aqueous solution is added and stirred;

[0060] (3) After thoroughly mixing, dry the mixed solid.

[0061] The solid active bromine bactericidal and algaecide is white powder or solid, has a light bromine smell and is easy to absorb moisture.

[006...

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PUM

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Abstract

The invention relates to a solid active bromine bactericidal algicide. The bactericidal algicide comprises, by weight, 30-40% of 2-bromine-4,5-dimethoxy phenyl propionitrile, 5-15% of 3-bromine-1-chlorine-5,5-dimethyl hydantoin, 5-15% of dibromo nitrilopropionamide, 15-25% of diquaternary ammonium activating agents, 10-20% of dibromo-2-cyanoacetamide and 5-15% of bronopol. The solid active bromine bactericidal algicide is advantageous in that, first, the bactericidal performances are strong and the bactericidal speed is fast; second, the application range of the pH value is wide; third, the bactericidal algicide is a bactericidal algicide with oxidizability and is effective to all kinds of microorganisms; fourth, the usage concentration is economical, and the bactericidal algicide with low dosage has strong bactericidal activity; fifth, the bactericidal algicide is suitable for ammonia-containing and nitrogen-containing water systems, and the bactericidal efficiency is not lowered with existence of ammonia; sixth, the bactericidal algicide has good intermiscibility and does not affect the using effects of corrosion and scale inhibitors; seventh, the bactericidal algicide has strong exfoliation; eighth, the bactericidal algicide has small impacts on the environment.

Description

Technical field [0001] The invention relates to the technical field of bactericidal and algaecide, in particular to the H-69 new solid active bromine bactericidal and algaecide in which the Yellow River water is applied to the circulating cooling water system as supplementary water and its preparation method Background technique [0002] At present, oxidative bactericidal algaecides have always used chlorine-containing bactericides, and the chlorine-containing bactericides generate hypochlorous acid after hydrolysis in water to achieve the sterilization effect. However, the shortcomings of chlorinated bactericides are also obvious. The effective bactericidal pH range of chlorinated bactericides is narrow. When the PH value of water is 7.5, more than 50% hypochlorous acid is dissociated, and when the pH value is 8.5, more than 90% times Chloric acid is dissociated, and hypochlorite radicals formed by dissociation have little bactericidal properties. [0003] However, bromine-contai...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N43/50A01P1/00A01P3/00A01P13/00C02F1/50
Inventor 朱海平郭宜平
Owner WUJIN HUADONG CHEM
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